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中国科学院大学学报 ›› 2001, Vol. 18 ›› Issue (2): 160-166.DOI: 10.7523/j.issn.2095-6134.2001.2.013

• 研究简报 • 上一篇    下一篇

根据螺旋理论推断脂肪族化合物的绝对构型

尹玉英, 刘春蕴   

  1. 北京石油化工学院化工系, 北京 102600
  • 收稿日期:2000-08-20 发布日期:2001-03-10
  • 作者简介:尹玉英,男,1933年3月生,副教授
  • 基金资助:

    国家自然科学基金资助项目(29542006)

The Predictoin of the Absolute Configuration of Aliphatic Compound

Yin Yuying, Liu Chunyun   

  1. Department of Chemical Engineering, Beijing Institute of Petro-chemical Technology, Beijing 102600
  • Received:2000-08-20 Published:2001-03-10

摘要:

脂肪族光学活性化合物,特别是链状化合物,可根据笔者提出的螺旋理论,对几个较稳定的构象进行计算,由计算结果和构象分析确定其旋光方向,再与测定的旋光方向相对照,同样可以推断出其绝对构型

关键词: 脂肪族化合物, 光学活性, 螺旋理论, 绝对构型推断

Abstract:

On the basis of the helix theory proposed by the authors, some stable conformations can be calculated especially chain compounds. According to the calculation and conformation analysis their rotatory direction will be ditermined, and the absolute configuration can be deduced.

Key words: aliphatic compound, optical activity, the helix theory, predictoin of the configuration

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