明宣德官窑祭红瓷器的呈色机制

doi:10.7523/j.issn.2095-6134.2016.03.020

中国科学院大学学报 ›› 2016, Vol. 33 ›› Issue (3): 421-426.DOI: 10.7523/j.issn.2095-6134.2016.03.020

明宣德官窑祭红瓷器的呈色机制

路辰¹, 江建新³, 徐长青⁵, 邬书荣³, 管理⁵, 张静⁴, 陈栋梁⁴, 徐伟⁴, 朱剑^1,2, 王昌燧^1,2

1. 中国科学院大学人文学院科技史与科技考古系, 北京 100049;
2. 中国科学院古脊椎动物与古人类研究所中国科学院脊椎动物演化与人类起源重点实验室, 北京 100044;
3. 景德镇陶瓷考古研究所, 江西景德镇 333001;
4. 中国科学院高能物理研究所, 北京 100049;
5. 江西省文物考古研究所, 南昌 330008

收稿日期:2015-06-15 修回日期:2015-11-20 发布日期:2016-05-15
通讯作者: 朱剑
基金资助:
国家自然科学基金(11275265,11205073,U1432243)和中国科学院科学技术史青年人才研教特别支持项目资助

Coloration mechanism of Xuande sacrificial red porcelain from Guan kiln of Jingdezhen in China

LU Chen¹, JIANG Jianxin³, XU Changqing⁵, WU Shurong³, GUAN Li⁵, ZHANG Jing⁴, CHEN Dongliang⁴, XU Wei⁴, ZHU Jian^1,2, WANG Changsui^1,2

1. Department of Scientific History and Archaeometry, University of Chinese Academy of Sciences, Beijing 100049,China;
2. Institute of Vertebrate Paleontology and Paleoanthropology, Key Laboratory of Vertebrate Evolution and Human Origins of Chinese Academy of Sciences, Beijing 100044,China;
3. Jingdezhen Ceramics Institute of Archaeology, Jingdezhen 333001, Jiangxi, China;
4. Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China;
5. Cultural Relics and Archaeology Institute of Jiangxi Province, Nanchang 330008, China

Received:2015-06-15 Revised:2015-11-20 Published:2016-05-15

摘要/Abstract

摘要：

采用多种无损方法,分析若干明宣德景德镇官窑祭红瓷器残片.显微观察表明,不同呈色区域表层都有相似的透明釉,其呈色差异主要取决于红色颜料层.成分分析显示,不同呈色样品的釉中着色剂Cu的含量基本相同.然而,X射线吸收精细结构(XANES)分析指出,不同呈色样品中着色剂Cu的价态和近边结构有所不同.由此可见,祭红的呈色机制与着色剂Cu的赋存状态密切相关.

关键词: 祭红, 显微结构, EDXRF, XANES, 呈色机理

Abstract:

Several shards of sacrificial red porcelain from Guan kiln of Jingdezhen during Xuande period were selected and study on the color mechanism was carried out using various non-destructive approaches. Microscopic observation shows that the different color areas have similar transparent glaze surfaces, and the color difference mainly depends on the red layer in glaze. Composition analysis results show that the contents of colorant copper for different color samples are almost the same. However, X-ray absorption fine structure (XANES) analysis reveals the differences in Cu chemical state among different hues of the samples. This indicates that the color mechanism of sacrificial red porcelain is closely related to the state of colorant copper.

Key words: sacrificial red porcelain, micro-structure, EDXRF, XANES, color mechanism

中图分类号:

K876.3

路辰, 江建新, 徐长青, 邬书荣, 管理, 张静, 陈栋梁, 徐伟, 朱剑, 王昌燧. 明宣德官窑祭红瓷器的呈色机制[J]. 中国科学院大学学报, 2016, 33(3): 421-426.

LU Chen, JIANG Jianxin, XU Changqing, WU Shurong, GUAN Li, ZHANG Jing, CHEN Dongliang, XU Wei, ZHU Jian, WANG Changsui . Coloration mechanism of Xuande sacrificial red porcelain from Guan kiln of Jingdezhen in China[J]. , 2016, 33(3): 421-426.

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明宣德官窑祭红瓷器的呈色机制

Coloration mechanism of Xuande sacrificial red porcelain from Guan kiln of Jingdezhen in China

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