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N,N′-双棕榈酰基乙二胺二乙酸钠的合成和表面活性

  • 廖文胜 ,
  • 毕只初
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  • 中国科学院化学研究所胶体与界面科学重点实验室, 北京 100080

收稿日期: 2003-06-09

  修回日期: 2003-08-12

  网络出版日期: 2004-05-10

基金资助

国家重点基础研究发展规划项目 (G1999022506)资助

Synthesis and Surface Properties of Anionic Gemini Surfactant of N, N′-Dipalmitoyl-Ethylenediamine-Diacetic Acid, Sodium Salt

  • LIAO WenSheng ,
  • BI ZhiChu
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  • Key Laboratory of Colloid and Interface Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China

Received date: 2003-06-09

  Revised date: 2003-08-12

  Online published: 2004-05-10

摘要

合成了新型阴离子Gemini表面活性剂N,N′双棕榈酰基乙二胺二乙酸钠,并以元素分析、1HNMR对合成的表面活性剂进行了表征;用表面张力法确定了其临界胶束浓度(cmc);对表面活性剂在硅胶上的润湿性进行了实验,发现其润湿性远优于十二烷基苯磺酸钠。

本文引用格式

廖文胜 , 毕只初 . N,N′-双棕榈酰基乙二胺二乙酸钠的合成和表面活性[J]. 中国科学院大学学报, 2004 , 21(3) : 340 -344 . DOI: 10.7523/j.issn.2095-6134.2004.3.009

Abstract

Anionic Gemini surfactant, N, N′ Dipalmitoyl ethylenediamine diacetic Acid, sodium salt, is synthesized and characterized by elemental analysis and 1HNMR. The critical micelle concentration (cmc) has been determined by means of surface tension measurements. Wettability of the surfactant aqueous solution on silica gel is far better than that of dodecylbenzenesulfonic acid, sodium salt.

参考文献

[1] Bi Zhi-Chu, Zhang Zhen-Shu, Xu Fei, Qian Yue-Ying, Yu Jia-Yong. Wettability, oil recovery, and interfacial tension with an SDBS-dodecane-kaolin system. Journal of Colloid and Interface Science, 1999, 214: 368-372

[2] Menger F M, Littau C A. Gemini surfactants: A new class of self-assembling molecules. J. Am. Chem. Soc., 1991, 113: 1451

[3] Rosen MJ. Geminis: A new generation of surfactants. Chemtech., 1993, 3: 30-33

[4] 北原文雄,早野茂夫,原一郎编. 毛培坤译. 表面活性剂分析和试验法. 北京:轻工业出版社,1988. 第一章

[5] Raoul Zana. Dimeric andoligomeric surfactants. Behavior at interfaces and in aqueous solution: a review. Advances in Colloid and Interface Science,2002, 97: 205-253

[6] Zhu Y P, Masuyama A, Kirito Y, Okahara M, Rosen MJ. Preparation and properties of glycerol2based double or triple-chain surfactants with two hydrophilic ionic Groups. J. Am. Oil. Chem. Soc., 1992, 69(7): 626-632

[7] Burnette L W. Sulfoalkyl esters and amides of fatty acids. In: Linfield W M, ed. Anionic Surfactant (part II). New York: Marcel Dekker, 1976

[8] Frederick C Bersworth. Process of purifying ethylene diamine Di-acetic acid. US Pat. 2 558 923, 1951

[9] Hans Konig. Nuclear magnetic resonance spectrometry of anionic surfactants. In: John Cross, ed. Anionic Surfactants-Chemical Analysis. New York: Marcel Dekker, 1977

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