收稿日期: 2001-04-16
修回日期: 2001-07-02
网络出版日期: 2002-03-18
基金资助
国家自然科学基金资助课题(10 14 5 0 0 6)
Further Study on the Analytical Solution of Schr dinger Equation of a Hydrogen-Like Atom
Received date: 2001-04-16
Revised date: 2001-07-02
Online published: 2002-03-18
张中良 , 张武寿 , 张兆群 . 类氢原子薛定谔方程解析解的进一步研究[J]. 中国科学院大学学报, 2002 , 19(2) : 186 -191 . DOI: 10.7523/j.issn.2095-6134.2002.2.016
Based on the previous works, the Schrdinger equation of the hydrogen-like atom is analytically solved further. Three sets of analytical solutions are obtained if the factor r~ -nis not neglected. The first solution is the same as the traditional radial wave function, the second diverges, and the last one is quite different from the traditional solution. On the consideration of the finite size of the nuclear, the third wave function does not diverge when r approaches to zero. Its radial wave function has the following characteristics: (1) the angular-momentum quantum number l must be greater than the principal quantum number n; (2) l must not be 0 or 1; (3) the electron-cloud distribution differs from the traditional one; (4) the electron is closer to the nuclear than that in traditional results. On the other hand, the validity of solutions needs to be verified experimentally.
Key words: hydrogen atom; hydrogen-like atom; Schringer equation
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