对二巯基苯促进的孔雀绿的芬顿降解
收稿日期: 2011-02-28
修回日期: 2011-03-23
网络出版日期: 2012-03-15
基金资助
Supported by NSFC (21007089), State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, CAS (KF2009-06), China Postdoctoral Science Foundation and the President Fund of GUCAS
Fenton degradation of malachite green promoted by 1,4-benzenedithiol
Received date: 2011-02-28
Revised date: 2011-03-23
Online published: 2012-03-15
Supported by
Supported by NSFC (21007089), State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, CAS (KF2009-06), China Postdoctoral Science Foundation and the President Fund of GUCAS
马家海 , 杨维英 , 李向军 . 对二巯基苯促进的孔雀绿的芬顿降解[J]. 中国科学院大学学报, 2012 , (2) : 175 -179 . DOI: 10.7523/j.issn.2095-6134.2012.2.005
In this study, we have found that the presence of 1,4-benzenedithiol (SH) could greatly accelerate Fenton reaction of dyes, such as malachite green and Rhodamine B, but could not improve the mineralization of those dyes. By performing cyclic voltammetry and 1,10-phenanthroline experiments we confirm that the effect of SH as a co-catalyst in the Fenton reaction is based on the accelerated cycle of Fe3+/Fe2+. We compare the effects of 1,4-benzenedithiol and 1,4-hydroquinone.
Key words： 1,4-benzenedithiol; malachite green; iron cycle; o-quinone
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