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物理学

类氦氪离子共振转移激发过程的理论研究

  • 胡骁骊 ,
  • 屈一至 ,
  • 王建国
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  • 1. 中国科学院研究生院材料科学与光电技术学院, 北京 100049;
    2. 北京应用物理与计算数学研究所, 北京 100088

收稿日期: 2012-03-26

  修回日期: 2012-04-20

  网络出版日期: 2012-04-20

基金资助

国家自然科学基金(1179041)和国家自然科学基金委-中国工程物理研究院联合基金(NSAF10876043)资助

Theoretical study on resonant transfer excitation processes for helium-like krypton ion

  • HU Xiao-Li ,
  • QU Yi-Zhi ,
  • WANG Jian-Guo
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  • 1. College of Materials Science and Opto-Electronic Technology, Graduate University, Chinese Academy of Sciences, Beijing 100049, China;
    2. Institute of Applied Physics and Computational Mathematics, Beijing 100088, China

Received date: 2012-03-26

  Revised date: 2012-04-20

  Online published: 2012-04-20

摘要

应用相对论组态相互作用方法,计算了类氦氪离子(Kr34+)经过1s2lnl'(n=2,3,…,15)态的双电子复合截面,然后在冲量近似下计算了Kr34+与CH4、NH3、H2O和HF共振转移激发(RTE)截面.在低动量端,CH4、NH3、H2O和HF的康普顿轮廓依次减小.相比Kr34+与CH4的RTE截面,Kr34+与NH3、H2O和HF的RTE截面在第1个峰位处截面值分别减小10.7%、23.3%和33.6%,在第2个峰位处截面值分别减小6.0%、12.3%和18.9%.同时,RTE峰的宽度依次增加,这表明随着C、N、O和F的核电荷数增加,库仑作用导致电子动量空间分布变大.

本文引用格式

胡骁骊 , 屈一至 , 王建国 . 类氦氪离子共振转移激发过程的理论研究[J]. 中国科学院大学学报, 2013 , 30(2) : 172 -178 . DOI: 10.7523/j.issn.1002-1175.2013.02.005

Abstract

The relativistic configuration interaction method is employed to investigate the resonant transfer excitation (RTE) processes of Kr34+ colliding with CH4, NH3, H2O, and HF targets under the impulse approximation. Compared to the case of CH4, the RTE cross sections of NH3, H2O, and HF targets reduce by 10.7%, 23.3%, and 33.6% in the first peak position and by 6.0%, 12.3%, and 18.9% in the second peak position, respectively, due to the decrease in Compton profiles in the small momentum region. On the other hand, the width of the peaks increases from CH4 to HF, which indicates that strong Coulomb effect leads to the broader momentum distribution.

参考文献

[1] Fuchs T,Biedermann C,Radtke R, et al.Channel-specific dielectronic recombination of highly charged krypton[J].Phys Rev A,1998,58(6):4518-4525.

[2] Tanis J,Bernstein E,Clark M W, et al.Resonant transfer and excitation: dependence on projectile charge state and target-electron momentum distribution[J].Phys Rev A,1986,34(3):2543-2546.

[3] Tanis J,Bernstein E,Graham W, et al.Resonant electron transfer and excitation in two-, three-, and four-electron 20Caq+ and 23Vq+ ions colliding with helium[J]. Phys Rev Lett,1984,53(27):2551-2554.

[4] Ma X,Mokler P,Bosch F, et al.Electron-electron interaction studied in strong central fields by resonant transfer and excitation with H-like U ions[J].Phys Rev A,2003,68(042712):1-10.

[5] Dong C Z,Fu Y B.Theoretical studies of dielectronic recombination and resonant transfer excitation for highly ionized Cu18+ ions[J].Chin Phys,2006,55:107-111(in Chinese).董晨钟,符彦飙.高离化态Cu18+离子的双电子复合及共振转移激发过程的理论研究[J].物理学报,2006,55:107-111.

[6] Dong C Z,Wang J G,Qu Y Z, et al.Dielectronic recombination and resonant transfer excitation for Ca19+ ions[J].Physica Scripta,1999,1999:301-302.

[7] Hehre W J,Ditchfield R, Pople J A.Self-consistent molecular orbital methods. XII. further extensions of Gaussian-type basis sets for use in molecular orbital studies of organic molecules[J].J Chem Phys,1972,56: 2257-2261.

[8] Krishnan R,Binkley J,Seeger R, et al.Self-consistent molecular orbital methods. XX. A basis set for correlated wave functions[J].J Chem Phys,1980,72:650-654.

[9] Kendall R A,Dunning Jr T H, Harrison R J.Electron affinities of the first-row atoms revisited. Systematic basis sets and wave functions[J].J Chem Phys,1992,96:6796-6806.

[10] Dunning Jr T H.Gaussian basis sets for use in correlated molecular calculations. I. The atoms boron through neon and hydrogen[J].J Chem Phys,1989,90:1007-1023.

[11] Woon D E, Dunning Jr T H.Gaussian basis sets for use in correlated molecular calculations. IV. Calculation of static electrical response properties[J].J Chem Phys,1994,100:2975-2988.

[12] Gu M F.Indirect X-ray line-formation processes in iron L-shell ions[J].Astrophy J,2003,582:1241-1250.

[13] Biedermann C,Fuchs T,Liebisch P, et al.X-ray spectroscopic measurements of dielectronic recombination of highly charged krypton ions[J].Physica Scripta,1999,1999:303-304.

[14] Brandt D.Resonant transfer and excitation in ion-atom collisions[J].Phys Rev A,1983,27:1314-1318.

[15] Eisenberger P.Electron momentum density of He and H2: Compton X-Ray scattering[J].Phys Rev A,1970,2:1678-1686.

[16] Brion C,Cooper G,Zheng Y, et al. Imaging of orbital electron densities by electron momentum spectroscopy-a chemical interpretation of the binary (e, 2e) reaction[J].Chem Phys,2001,270:13-30.

[17] Frisch M,Trucks G,Schlegel H, et al.Gaussian 98, revision A. 7[CP].Pittsburgh, PA:Gaussian Inc,1998.

[18] Linstrom P J, Mallard W.The NIST Chemistry WebBook[DB/OL].(1997)[2012-02-25]. http://webbook.nist.gov/chemistry.

[19] Ahlenius T, Lindner P.Compton profiles and momentum expectation values for the H2O, NH3 and CH4 molecules[J].Chem Phys Lett,1975,34:123-127.

[20] Hu X L,Qu Y Z,Zhang S B, et al.Dielectronic recombination and resonant transfer excitation processes for helium-like krypton[J].Chin Phys B, 2012, 21(10):220-226.

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