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煤层气产出水中高浓度Cl-和HCO3-对活性氧化铝吸附F-的动力学影响

  • 黄丽娟 ,
  • 胡正义 ,
  • 卢佳 ,
  • 鲍鹏 ,
  • 刘小宁 ,
  • 周国慧
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  • 中国科学院研究生院资源与环境学院, 北京 100049

收稿日期: 2012-03-06

  修回日期: 2012-03-30

  网络出版日期: 2012-03-30

基金资助

国家科技重大专项(2011ZX05060-005,2008ZX05039-003)资助

Influence of Cl- and HCO3- ions on adsorption kinetics of F- on activated alumina in coalbed methane co-produced water

  • HUANG Li-Juan ,
  • HU Zheng-Yi ,
  • LU Jia ,
  • BAO Peng ,
  • LIU Xiao-Ning ,
  • ZHOU Guo-Hui
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  • College of Resources and Environment, Graduate University, Chinese Academy of Sciences, Beijing 100049, China

Received date: 2012-03-06

  Revised date: 2012-03-30

  Online published: 2012-03-30

摘要

通过静态试验研究了高质量浓度Cl-(1000 mg·L-1)和HCO3-(2000 mg·L-1)对活性氧化铝吸附F-(10 mg·L-1)的动力学特性影响.结果表明:高质量浓度Cl-使活性氧化铝吸附F-速率加快,吸附量增加;高质量浓度HCO3-有相反趋势.建议采用活性氧化铝吸附除氟法作为煤层气产出水F-净化工艺时,考虑高质量浓度Cl-和HCO3-效应.

本文引用格式

黄丽娟 , 胡正义 , 卢佳 , 鲍鹏 , 刘小宁 , 周国慧 . 煤层气产出水中高浓度Cl-和HCO3-对活性氧化铝吸附F-的动力学影响[J]. 中国科学院大学学报, 2013 , 30(2) : 213 -219 . DOI: 10.7523/j.issn.1002-1175.2013.02.011

Abstract

Activated alumina (AA) is widely used for defluoridation. Batch experiments were carried out to investigate the influence of Cl- (1000 mg·L-1) and HCO3- (2000 mg·L-1) on adsorption kinetics of F- (10 mg·L-1) on AA in coalbed methane co-produced water (CBMW). The results show that in the presence of Cl- the adsorption rate and the equilibrium absorption capacity increase, but in the presence of HCO3- both the quantities decrease. These effects should be considered when one treats CBMW.

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