欢迎访问中国科学院大学学报,今天是
环境科学与地理学

煤渣吸附水中氟和砷的研究

  • 李娟 ,
  • 刘新春 ,
  • 余志晟 ,
  • 易鑫 ,
  • 琚宜文
展开
  • 1. 中国科学院大学资源与环境学院, 北京 100049;
    2. 中国科学院大学地球科学学院, 北京 100049

收稿日期: 2013-05-22

  修回日期: 2013-09-30

  网络出版日期: 2014-07-15

基金资助

国家科技重大专项(2011ZX05060-005)资助

Study on adsorption of fluorine and arsenic in water by coal cinder

  • LI Juan ,
  • LIU Xinchun ,
  • YU Zhisheng ,
  • YI Xin ,
  • JU Yiwen
Expand
  • 1. College of Resources and Environment, University of Chinese Academy of Sciences, Beijing 100049, China;
    2. College of Earth Science, University of Chinese Academy of Sciences, Beijing 100049, China

Received date: 2013-05-22

  Revised date: 2013-09-30

  Online published: 2014-07-15

摘要

采用煤渣静态吸附水中氟和砷.考察煤渣投加量、震荡时间、进水浓度和pH值对煤渣吸附性能的影响.实验结果表明,每100 mL污水较为合适的煤渣用量为6 g;煤渣对氟和砷的最佳吸附时间为3 h;对高氟水的吸附效果较好,对低氟水的去除效果相对较差;对高浓度及低浓度的砷均具有较好的吸附效果,去除率均达到95%以上;pH值对氟和砷的吸附影响不大.

关键词: 煤渣; ;

本文引用格式

李娟 , 刘新春 , 余志晟 , 易鑫 , 琚宜文 . 煤渣吸附水中氟和砷的研究[J]. 中国科学院大学学报, 2014 , 31(4) : 471 -476 . DOI: 10.7523/j.issn.2095-6134.2014.04.005

Abstract

The adsorption characteristics of coal cinder to fluorine and arsenic were studied with static adsorption experiments, and the influences of oscillation time, sorbent dosage, initial concentration, and pH on the adsorption characteristics were investigated. The results show that in the optimal processes sorbent dosage is 6 g and adsorption time is 3 h. Adsorption of fluorine by coal cinder is more effective at higher concentration of fluorine than at lower concentration. However, adsorption rates of arsenic are always more than 95%,whatever the initial concentrations. The acidity has little influence on the adsorption characteristics of fluorine and arsenic.

Key words: coal cinder; fluorine; arsenic

参考文献

[1] Cui Y S, Ju Y W. Coal bed methane produced water quality and its impact on soil and plant: a review[J]. Environmental Science & Technology, 2011,34(11):25-30(in Chinese). 崔岩山,琚宜文.煤层气采出水水质及其对土壤和植物影响研究进展[J].环境科学与技术,2011,34(11):25-30.

[2] Huang L J, Hu Z Y, Lu J,et al. Influence of Cl-and HCO3- ions on adsorption kinetics of F- on activated alumina in coal bed methane co-produced water[J].Journal of Graduate University of Chinese Academy of Sciences,2013,30(2) :213-219(in Chinese). 黄丽娟,胡正义,卢佳,等.煤层气产出水中高浓度Cl-和HCO3-对活性氧化铝吸附F-的动力学影响[J].中国科学院研究生院学报,2013:30(2):213-219.

[3] Lian G Q, Hu J W, Qin P X, et al. Progress in study on hazards and detection methods of fluorine[J]. Endemic Diseases Bulletin,2008,23(5):125-127(in Chinese). 连国奇,胡继伟,秦攀鑫,等.氟对人体的危害及检测方法研究进展[J].地方病通报,2008,23(5):125-127.

[4] Zhao L B, Liang G H, Zhang D N, et al. Effect of a high fluoride water supply on children's intelligence[J]. Fluoride, 1996, 29 (4):190-192.

[5] Seraj B, Shahrabi M, Shadfar M, et al. Effect of high water fluoride concentration on the intellectual development of children in makooiran[J]. Journal of Dentistry, 2012, 9(3):221-229.

[6] 邱立萍.砷污染危害及其治理技术[J].新疆环境保护,1999,21(3): 15-19.

[7] 李典友,陆亦农. 土壤中砷污染的危害及防治对策研究[J].新疆师范大学学报,2005,24(4):89-91.

[8] NRC. Arsenic in drinking water: 2001 Update[R]. National Research Council. Washington D C: National Academy Press, 2001.

[9] Astolfi E, Maccagno A, Garcia Fenandez J C, et al. Relation between Arsenic in drinking water and Skin Cancer[J]. Biological Trace Element Research, 1981, 2:133-143.

[10] Guo H R, Tseng Y C. Arsenic in drinking water and bladder cancer: Comparison between studies based on cancer registry and death certificates[J]. Environmental Geochemistry and Health, 2000, 2:83-91.

[11] Kumar V, Talreja N, Deva D, et al, Development of bi-metal doped micro-and nano multi-functional polymeric adsorbents for the removal of fluoride and arsenic(V) from wastewater [J]. Desalination, 2011, 282: 27-38.

[12] Chen H X, Luo X P, Liu L L. Research on the progress of waste water of fluorine containing[J]. Sichuan Nonferrous Metals,2006(1):31-35(in Chinese). 陈后兴,罗仙平,刘立良.含氟废水处理研究进展[J].四川有色金属,2006,(1):31-35.

[13] Yan Q, Yu Y, Zhou N N. Research development of arsenic removal from drinking water[J]. Nonferrous Metals Science and Engineering,2012,3(3):74-79(in Chinese). 严群,余洋,周娜娜. 饮用水中砷处理技术研究进展[J].有色金属科学与工程,2012,3(3):74-79.

[14] 李永富,孟范平,姚瑞华.饮用水除氟技术开发应用现状[J].水处理技术,2010,36(7):10-13.

[15] Yao J J, Gao N Y, Xia S J, et al. Research progress on arsenic removal from drinking water[J]. Industrial Water & Wastewater,2007,38(4):1-5(in Chinese). 姚娟娟,高乃云,夏圣骥,等.饮用水除砷技术研究新进展[J].工业用水与废水,2007,38(4): 1-5.

[16] 李林永,王敦球,张华,等.煤渣作为人工湿地除磷基质的性能评价[J].桂林理工大学学报,2011,31(2):246-251.

[17] Wan B J, Lü X, Wu X F. Study on the adsorption influent factors of zinc by cinder[J]. Science and Technology of West China,2009,8(7):17-19(in Chinese). 万邦江,吕昕,吴兴发.煤渣吸附锌的影响因素研究[J].中国西部科技,2009,8(7):17-19.

[18] Li X L, Liu J F, Li P Y. Principle and application of fluoride removal by lime sedimentation method[J]. Technology of Water Treatment, 2000,26(6):359-361(in Chinese). 李雪玲,刘俊峰,李培元.石灰沉淀法除氟的应用[J].水处理技术,2000,26(6):359-361.

[19] Zhou Y M, Yu C X. Development on dealing with F-containing wastewater using adsorption methods[J]. Ion Exchange and Adsorption, 2001,17(5):369-376(in Chinese). 周钰明,余春香. 吸附法处理含氟废水的研究进展[J].离子交换与吸附,2001,17(5):369-376.

[20] Jia X Q. High concentration arsenic-containing waste water treatment and recycle works [J]. SP & BMH Related Engineering, 2005,5(4):42-45(in Chinese). 贾秀芹.高浓度含砷废水处理回用工程[J].硫磷设计与粉体工程,2005,5(4):42-45.

[21] 赵振国.吸附作用应用原理[M].北京:化学工业出版社,2005:173-176.

[22] Zheng L X, Qiao D L, Qian P J, et al. The application study on urban sewage secondary effluent with boiler coal cinders[J]. Energy Environmental Protection,2011,26(3):23-29(in Chinese). 郑利祥,乔大磊,钱培金,等.锅炉煤渣在城市污水二级出水中的运用研究[J].能源环境保护,2011,26(3):23-29.

[23] Shen X W, Fan J B, Huang J, et al. Experimental research on treatment of fluoride-containing wastewater by the bone bar which was modified by ssing Al2(SO4)3 [J]. Science Mosaic, 2011,3:202-206(in Chinese). 沈小娃,范景彪,黄俊,等. Al2(SO4)3改性骨炭吸附含氟废水的实验研究[J].科技广场,2011,3:202-206.

[24] Hua G F,Liu H F,Wu X R,et al. Experimental study of fluorine removal capacity of activated aluminum oxide [J]. Ground Water,2009,31(2):113-116(in Chinese). 华根福,刘焕芳,吴心蓉,等.活性氧化铝出氟性能的试验研究[J].地下水,2009,31(2):113-116.

[25] Zhang Y Q. Study on removement of trace arsenic in groundwater by activated alumina [J]. Environmental Monitoring and Forewarning, 2010,2(3):50-56(in Chinese) . 张玉琴.活性氧化铝去除地下水中微量砷的实验[J].环境监控与预警,2010,2(3):50-56.

文章导航

/