收稿日期: 2000-08-20
网络出版日期: 2001-03-10
基金资助
国家自然科学基金资助项目(29542006)
The Predictoin of the Absolute Configuration of Aliphatic Compound
Received date: 2000-08-20
Online published: 2001-03-10
尹玉英 , 刘春蕴 . 根据螺旋理论推断脂肪族化合物的绝对构型[J]. 中国科学院大学学报, 2001 , 18(2) : 160 -166 . DOI: 10.7523/j.issn.2095-6134.2001.2.013
On the basis of the helix theory proposed by the authors, some stable conformations can be calculated especially chain compounds. According to the calculation and conformation analysis their rotatory direction will be ditermined, and the absolute configuration can be deduced.
1 尹玉英, 刘春蕴.立体化学中旋光性与结构关系的新理论.中国科学院研究生院学报, 1998, 15(1):30 ～ 37
2 Brew ster J H.Heli x M odels of O ptical A ctivity.Top S tereochemist ry.Vol.2.New Y ork :John W iley & S ons, 1967.1 ～ 72
3 Fric I S pi rko V, Blaha K.Amino A cids and Peptides L X X X V II.O ptical Rot at ory D ispersion of Some β-aryl-α- amino A cids and M odel Compounds.Collect Czech Chem Commen, 1968, 33(12):4008 ～ 4026
4 Ivanova T M, A rk hi pova S F, Kugat ova-Shenyakina G P.A nalysis of the Conformat ion of A li phatic A lcohols and Et hers.Iz v Akad Nauk SSS R, Ser K him, 1973, 7 :1521 ～ 1526
5 Lane J F, Wallis E S.M olecular Rearrangement s Involving O ptically A ct ive Radicals X.Retent ion of Configurati on in the Wolf f Rearrange-ment.J A m Chem Soc, 1941, 63 :1674
6 S uga T, O hta S, A oki T, et al.T he Fact ors Domi nating the Reversal in t he S ense of t he O ptical Rotation of Diarylhept anoi ds in Solvents of Diff eren t Nature.Chem Let t, 1985,(9):1331 ～ 1334
7 Potapov V M.S tereochemist ry.M oscow :M IR Publishers, 1979.472
/
| 〈 |
|
〉 |
