张惠珍 , 刘白玲 , 罗荣 . PVA及其复合材料生物降解研究进展[J]. 中国科学院大学学报, 2005 , 22(6) : 657 -666 . DOI: 10.7523/j.issn.2095-6134.2005.6.001

[1] Ge JF.Biodegradable Polymer Materials and Applications.Beijing:Chemical Industry Press,2002 (in Chinese).

[2] Chiellini E.Biodegradation of Poly (vinyl alcohol) based materials.Prog.Polym.Sci.,2003,28:963～1014.

[3] Zhang X,Du GC,Chen J.Developments in study of Poly (vinyl alcohol) degrading enzyme.Journal of Chinese Biotechnol. 2003,23 (2):69～73 (in Chinese with English abstract).

[4] Raghavan D.Characterization of biodegradable plastics.Polym-Plast Technol.Eng.,1995,34 (1):41～63.

[5] Fujita M,Ike M,Kawagoshi Y.Bioteatment of persistent substances using effective microorganisms.Water Science &Technology,2000,42 (12):93～106.

[6] Watanabe Y,Morita M,Hamada N,et al.Formation of hydrogen peroxide by a polyvinyl alcohol degrading enzyme.Agric Biol.Chem.,1975,39:2447～2448.

[7] Morita M,Watanabe Y.A secondary alcohol oxidase:a component of a polyvinyl alcohol degrading enzyme preparation.Agric Biol.Chem.,1977,41:1535～1537.

[8] Suzuki T,Ichihara Y,Yamada M,et al.Some characteristics of Pseudomonas O-3 which utilizes polyvinyl alcohol.Agric Biol.Chem.,1973,37:747～756.

[9] Sakai K,Fukuda M,Hasui Y,et al.Purification and characterization of an esterase involved in Poly (vinyl alcohol) degradation by Pseudomonas vesicularis PD.Biosci.Biotechnol.Biochem.,1998,62:2000～2007.

[10] Sakazawa C,Shimao M,Taniguchi Y,et al.Symbiotic utilization of Poly (vinyl alcohol) by mixed cultures.Appl.Environ.Microbiol.,1981,41:261～267.

[11] Mori T,Sakimoto M,Kagi T,et al.Isolation and characterization of a strain of Bacillus megaterium that degrades Poly(vinyl alcohol).Biosci.Biotechnol.Biochem.,1996,60:330～332.

[12] Lee JA,Kim MN.Isolation of new and potent Poly (vinyl alcohol) degrading strains and their degradation activity.Polym.Degrad.Stab.,2003,81:303～308.

[13] Porter JJ,Snider EH.Thirty day biodegradability of textile chemicals and dyes.Book Pap,Natl Tech Conf AATCC.1974.427～436.

[14] Ine's Mejy'a AG,Lucy Lo'pez BO,Mulet AP.Biodegradation of Poly (vinyl alcohol) with enzymatic extracts of phanerochaete chrysosporium.Macromol.Symp.,1999,148:134～147.

[15] Lopez BL,Ine's Mejy'a AG,Sierra GL.Biodegradability of Poly (vinyl alcohol).Polym.Engng.Sci.,1999,39:1346～1352.

[16] Mori T,Sakimoto M,Kagi T,et al.Secondary alcohol dehydrogenase from a vinyl alcohol oligomer-degrading geotrichumfermentans ; stabilization with Triton X-100 and activity towards Polymers with Polymerization degrees less than 20.World J.Microbiol.Biotechnol.,1998,14:349～356.

[17] Matsumura S,Toshima K.Biodegradation of Poly (vinyl alcohol) and vinyl alcohol block as biodegradable segments.In:Ottenbrite RM,Huang SJ,Park K,editors.Hydrogels and Biodegradable Polymers for Bioapplications.New York:Wiley,1992.767～772.

[18] Chiellini E,Corti A,Solaro R.Biodegradation of Poly (vinyl alcohol) based blown films under different environmental conditions.Polym.Degrad.Stab.,1999,64:305～312.

[19] Corti A,Solaro R,Chiellini E.Biodegradation of Poly (vinyl alcohol) in selected mixed microbial culture and relevant culture filtrate.Polym.Degrad.Stab.,2002,75:447～458.

[20] Haschke H,Tomka I,Keilbach A.Systematic investigations on the biological degradability of packing material.Part 21 On the biodegradability of poly(vinyl alcohol)2based films.Monatsh.Chem.,1998,129:365～386.

[21] Yamamoto T,Yoda S,Sangen O,et al.Preparation and saponification of high molecular weight Poly (vinyl privalate).Polym.J.,1989,21:1053～1054.

[22] Fukae R,Fuji T,Takeo M,et al.Biodegradation of Poly (vinyl alcohol) with high isotacticity.Polym.J.,1994,26:1381～1386.

[23] Liu BL,Zeng XC,Yang JH.Influencing factors on Biodegradation of Poly (vinyl alcohol).Vinylon Communication,1998,18 (4):12～16 (in Chinese).

[24] Tetsuya I,Naoko Y,Yoshio I.Influence of tacticity and molecular weight of Poly (vinyl alcohol) on crystallization and biodegradation of Poly (32 hydroxybutyric acid)PPoly (vinyl alcohol) blend films.Polym.Degrad.Stab.,1999,66:263～270.

[25] Shimao M,Taniguchi Y,Shikata S,et al.Production of polyvinyl alcohol oxidase by a symbiotic mixed culture.Appl.Environ.Microbiol.,1982,44:28～32.

[26] Chiellini E,Corti A,Solaro R.Biodegradation of Poly (vinyl alcohol) based blown films under different environmental conditions.Polym.Degrad.Stab.,1999,64:305～312.

[27] David C,De Kesel C,Lefebvre F,et al.The biodegradation of polymers:recent results.Angew.Makromol.Chem.,1994,216:21～35.

[28] Chiellini E,Corti A,Solaro R,et al.Environmentally degradable plastics:Poly (vinyl alcohol)-a case study.In:Said ZF,Chiellini E,editors.International workshop on environmentally degradable polymers:polymeric materials and the environment.Doha Qatar March,21～25.1999.103～118.

[29] Matsumura S,Kurita H,Shimokobe H.Anaerobic biodegradability of polyvinyl alcohol.Biotechnol.Lett.,1993,15:749～754.

[30] Nishio Y,Manley R,St J.CellulosePPoly ( vinyl alcohol ) blends prepared from solutions in N,N-dimethylacetamide-lithium chloride.Macromolecules,1988,21:1270～1277.

[31] Nishio Y,Haratani T,Takahashi T.CellulosePPoly (vinyl alcohol) blends:an estimation of thermodynamic polymer2polymer interaction by melting point depression analysis.Macromolecules,1989,22:2547～2549.

[32] Chiellini E,Cinelli P,Corti A,et al.Environmentally sound blends and composites based on water2soluble polymer matrices.Macromol.Symp.,2000,152:83～94.

[33] Shimao M,Taniguchi Y,Shikata S,et al.Production of polyvinyl alcohol oxidase by a symbiotic mixed culture.Appl.Environ.Microbiol.,1982,44:28～32.

[34] Chiellini E,Cinelli P,Chiellini F,et al.Environmentally degradable bio-based polymeric blends and composites.Macromol.Biosci.,2004,4(3):218～231.

[35] Otey FH,Mark AM,Mehltretter CL,et al.Starchbased filmfor degradable agricultural mulch.Ind.Engng.Chem.Prod.Res.Dev.,1974, 13:90～92.

[36] Ishigaki T,Kawagoshi Y,Ike M,et al.Biodegradation of a polyvinyl alcohol-starch blend plastic film.World J.Microbiol.Biotechnol.,1999,15:321～327.

[37] Wang T,Turhan M,Gunasekaran S.Selected properties of pH2sensitive,biodegradable chitosan2Poly ( vinyl alcohol ) hydrogel.Polymer International,2004,53 (7):911～918.

[38] Takasu A,Aoi K,Tsuchiya M,et al.New chitin2based polymer hybrids.Part 41 Soil burial degradation behavior of Poly (vinyl alcohol)Pchitin derivative miscible blends.J.Appl.Polym.Sci.,1999,73:1171～1179.

[39] Chiellini E,Cinelli P,Corti A,et al.Composite films based on waste gelatin:thermal-mechanical properties and biodegradation testing.Polym.Degrad.Stab.,2001,73:549～555.

[40] Zhao L,Tsuchiya K,Inoue Y.Fully-biodegradable Poly ( 3-hydroxybutyrate )/Poly ( vinyl alcohol ) blend films with compositional gradient.Macromol.Biosci.,2004,4 (8):699～705.

[41] Kumagai Y.Enzymatic degradation of microbial poly (32hydroxybutyrate).Makromol.Chem.,1992,193:53～57.

[42] Ikejima T,Cao A,Yoshie N,et al.Surface composition and biodegradability of poly (3-hydroxybutyric acid)/Poly (vinyl alcohol) blend films.Polym.Degrad.Stab.,1998,62:463～469.

[43] De Kesel C,Vander WC,David C.Biodegradation of polycaprolactone and its blends with Poly (vinyl alcohol) by microorganisms from a compost of house-hold refuse.Polym.Degrad.Stab.,1997,55:107～113.

[44] Katoh K,Shibayama M,Tanabe T,et al.Preparation and properties of keratin2Poly(vinyl alcohol) blend fiber.J.Appl.Polym.Sci.,2004,91 (2):756～762.

[45] Matsumura S,Tanaka T.Novel malonate-type copolymers containing vinyl alcohol blocks as biodegradable segments and their builder performance in detergent formulations.J.Environ.Polym.Degrad.,1994,2:89～97.

[46] Agrade AB,Peppas NA.Poly (acrylic acid)2Poly (vinyl alcohol) copolymers with superabsorbent properties.J.Appl.Polym.Sci.,1998,70:817～829.

[47] Okaya T,Ikari K.Ethylene-vinyl alcohol copolymers.In:Finch CA,editor.Polyvinyl Alcohol Developments.Chicester:Wiley,1992.195～268.

[48] Bastioli C,Bellotti V,Del Giudice L,et al.Mater-Bi:properties and biodegradability.J.Environ.Polym.Degrad.,1993,1:181～191.

[49] Takasu A,Itou H,Takada M,et al.Accelerated biodegradation of Poly (vinyl alcohol) by a glycosidation of the hydroxyl groups.Polymer,2002,43:227～231.

[50] Tokiwa Y,Fan H,Hiraguri Y,et al.Biodegradation of a sugar branched polymer consisting of sugar,fatty acid,and Poly (vinyl alcohol).Macromolecules,2000,33:1636～1639.