岩石的吸水现象广泛存在于自然界与人为工程中,而毛细作用是非饱和状态下水分运移的主要驱动力,其规律研究具有重要科学意义与实际价值。针对水分运移难以监测的问题,将核磁共振技术用于人工砂岩吸水特性及其影响因素的研究,利用T2谱分析样品孔隙水分变化,一维剖面成像获取其水分迁移信息。从实验结果可知,孔隙较大、连通性较好的砂岩吸水量大、吸水速率快。定量计算得到样品一维吸水率约为0.036 8 cm/min1/2。此外,研究发现实验过程中的蒸发效应会对吸水过程产生不容忽视的影响。与称重法、CT法等相比,核磁共振实验研究具有快速直观、高精度、信息全面的优势。
Characterization of water imbibition in porous media is important in a variety of engineering and geological contexts.This work is aimed at investigating sorption characteristics of sandstones and how they are related to the pore structure of samples and boundary conditions.Over the past decades,NMR techniques have been proven to be reliable for visualizing the water distribution and quantifying the dynamic transport process of water in porous media.In this study,Carr-Purcell-Meiboom-Gill (CPMG) measurement was used to obtain the T2 distribution which showed the change in water content in pores of different sizes with time.Moreover,one-dimensional magnetic resonance imaging (MRI) profile measurement was used to obtain the water content profiles during water imbibition into artificial sandstone samples in a quantitative and non-destructive manner.In order to understand the characteristics of water absorption and factors influencing the process,results of imbibition in samples of different permeability were compared by performing one-dimensional and three-dimensional NMR experiments.Sorptivity based on Fickian diffusion was adopted to make a quantitative analysis of sandstone samples. The results showed that sample of high permeability had a greater amount of water absorption with less time.In addition,the cumulative water absorption varied linearly with t1/2 as expected.Therefore the sorptivity was derived directly to be 0.036 8 cm/min1/2 with the correlation coefficient r=0.996 7.However,the increase of water content slowed down after the wetting front reached the top of the sample,which could be explained by the retarding effect of evaporation on the sample surface.
[1] 李天斌, 陈子全, 陈国庆,等. 不同含水率作用下砂岩的能量机制研究[J]. 岩土力学, 2015(s2):229-236.
[2] Lockington D, Parlange J Y, Dux P. Sorptivity and the estimation of water penetration into unsaturated concrete[J]. Materials & Structures, 1999, 32(5):342-347.
[3] Leventis A, Verganelakis D A, Halse M R, et al. Capillary imbibition and pore characterisation in cement pastes[J]. Transport in Porous Media, 2000, 39(2):143-157.
[4] Dehghanpour H, Lan Q, Saeed Y, et al. Spontaneous imbibition of brine and oil in gas shales:effect of water adsorption and resulting microfractures[J]. Energy & Fuels, 2013, 27(6):3039-3049.
[5] Engelder T, Cathles L M, Bryndzia L T. The fate of residual treatment water in gas shale[J]. Journal of Unconventional Oil & Gas Resources, 2014, 7:33-48.
[6] 蔡建超, 郁伯铭. 多孔介质自发渗吸研究进展[J]. 力学进展, 2012, 42(6):735-754.
[7] 黄蓓, 钱春香. 掺合料混凝土的毛细吸水现象[J]. 混凝土与水泥制品, 2008(4):14-16.
[8] 李淑红, 王立成. 多孔建筑材料毛细吸水过程研究进展综述[J]. 水利与建筑工程学报, 2010, 8(6):16-20.
[9] Washburn E W. The dynamics of capillary flow[J]. Physical Review, 1921, 17(3):273-283.
[10] Fries N, Dreyer M. An analytic solution of capillary rise restrained by gravity[J]. Journal of Colloid & Interface Science, 2008, 320(1):259-263.
[11] Kim E, Whitesides G M. Imbibition and flow of wetting liquids in noncircular capillaries[J]. Journal of Physical Chemistry B, 1997, 101(6):855-863.
[12] Cai J, Yu B, Zou M, et al. Fractal characterization of spontaneous co-current imbibition in porous media[J]. Energy & Fuels, 2010, 24(1):1860-1867.
[13] 李科, 贾志刚, 余宏明,等. 石膏质岩毛细吸水特性与孔隙特征研究[J]. 长江科学院院报, 2014, 31(9):79-83.
[14] 任凯, 葛洪魁, 杨柳,等. 页岩自吸实验及其在返排分析中的应用[J]. 科学技术与工程, 2015, 15(30):106-109.
[15] 贾志刚, 齐平, 李科,等. 岩石毛细吸水试验新方法[J]. 长江科学院院报, 2015(5):95-99.
[16] 查甫生, 刘松玉, 杜延军,等. 基于电阻率法的膨胀土吸水膨胀过程中结构变化定量研究[J]. 岩土工程学报, 2008(12):1832-1839.
[17] Roels S, Carmeliet J. Analysis of moisture flow in porous materials using microfocus X-ray radiography[J]. International Journal of Heat & Mass Transfer, 2006, 49(s 25/26):4762-4772.
[18] Hanzic, Ilic R. Relationship between liquid and capillary in concrete[J]. Cement and Concrete Research, 2003, 33(9):1385-1388.
[19] 蒙冕模, 葛洪魁, 纪文明,等. 基于核磁共振技术研究页岩自发渗吸过程[J]. 特种油气藏, 2015(5):137-140.
[20] Holmes W M, Packer K J. Investigation of two phase flow and phase trapping by secondary imbibition within Fontainebleau sandstone[J]. Magnetic Resonance Imaging, 2003, 21(s 3/4):389-391.
[21] 周莉, 何满潮, 李京阳,等. 砂岩吸水特性试验[J]. 解放军理工大学学报(自然科学版), 2009, 10(6):580-585.
[22] 司文朋, 魏建新, 狄帮让,等. 人造砂岩制作方法及其声学性质研究[J]. 地球物理学进展, 2013, 28(4):2193-2198.
[23] Nestle N. NMR relaxometry study of cement hydration in the presence of different oxidic fine fraction materials[J]. Solid State Nuclear Magnetic Resonance, 2004, 25(1/3):80-83,84.
[24] Tziotziou M, Karakosta E, Karatasios I, et al. Application of 1H NMR to hydration and porosity studies of lime-pozzolan mixtures[J]. Microporous & Mesoporous Materials, 2011, 139(1-3):16-24.
[25] 俎栋林. 核磁共振成像学[M]. 北京:高等教育出版社, 2004.
[26] Jiang T, George Hirasaki A, Miller C, et al. Diluted bitumen water-in-oil emulsion stability and characterization by nuclear magnetic resonance (NMR) measurements†[J]. Energy & Fuels, 2007, 21(3):1325-1336.
[27] Sabir B B, Wild S, O'Farrell M. A water sorptivity test for mortar and concrete[J]. Materials & Structures, 1998, 31(8):568-574.
[28] Martys N S, Ferraris C F. Capillary transport in mortars and concrete[J]. Cement & Concrete Research, 1997, 27(5):747-760.
[29] Wilson M A, Hoff W D, Hall C. Water movement in porous building materials-XI. Capillary absorption from a hemispherical cavity[J]. Building & Environment, 1994, 29(1):99-104.
[30] Roels S. A comparison of different techniques to quantify moisture content profiles in porous building materials[J]. Journal of Thermal Envelope & Building Science, 2004, 27:261-276.
[31] Lockington D A, Parlange J Y, Lenkopane M. Capillary absorption in porous sheets and surfaces subject to evaporation[J]. Transport in Porous Media, 2007, 68(1):29-36.