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聚丙烯三相结构长周期的小角X射线散射研究

  • 刘开源 ,
  • 赵辉 ,
  • 李志宏 ,
  • 董宝中
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  • 1. 鞍山师范学院物理系, 鞍山 114005;
    2. 中国科学院高能物理研究所同步辐射实验室, 北京 100049

收稿日期: 2004-02-23

  修回日期: 2004-06-02

  网络出版日期: 2005-03-15

Small Angle X-ray Scattering Study on Long Periods of Polypropylene Three-phase Structure

  • LIU Kai-Yuan ,
  • ZHAO Hui ,
  • LI Zhi-Hong ,
  • DONG Bao-Zhong
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  • 1. Department of Physics, Anshan Normal College, Anshan 114005, China;
    2. Synchrotron Radiation Laboratory, Institute of High Energy Ph ysics, Chinese Academy of Sciences, Beijing 100049, China

Received date: 2004-02-23

  Revised date: 2004-06-02

  Online published: 2005-03-15

摘要

应用小角X射线散射技术研究了聚丙烯的长周期,结果表明,聚丙烯的相关函数长周期与它的Bragg长周期不相等;应用小角散射理论和结晶聚合物的三相结构模型研究了聚丙烯的2种长周期不同的原因,得到结论,聚丙烯的Bragg长周期接近于它的相关函数长周期与结晶过渡层的厚度之和.这个结论与小角散射实验的结果一致.

本文引用格式

刘开源 , 赵辉 , 李志宏 , 董宝中 . 聚丙烯三相结构长周期的小角X射线散射研究[J]. 中国科学院大学学报, 2005 , 22(2) : 135 -139 . DOI: 10.7523/j.issn.2095-6134.2005.2.002

Abstract

In the paper, small angle X-ray scattering technique was used to study long periods of polypropylene.The results indicate that the correlation function long period of polypropylene and its Bragg long period are not identical. We applied the theory of small-angle scattering and three-phase model of crystalline polymer to study the reason of differences of two kinds of long periods of polypropylene and draw a conclusion that the Bragg long period approaches the correlation function long period plus the thickness of the transition layer. The conclusion is consistentwith our small-angle scattering experimental results.

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