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The Existence of Isosteroidal Alkaloids in Fritillaria L.(Liliaceae) and Its Taxonomical Significance

Yu Shi-Chun, Xiao Pei-Gen   

  • Received:1900-01-01 Revised:1900-01-01 Online:1992-09-10 Published:1992-09-10
  • Contact: Yu Shi-Chun

Abstract:

 The plant chemotaxonomical marker of Fritillaria L. is discussed in this
paper according to the information on chemical components. Plenty of evidence
shows that 5α-cevanine isosteroidal alkaloids are the characteristic constituents of
this genus. In the light of the biogensis of this kind of alkaloids, the C-13 and
C- 17 of the molecular structures may be rational positions uniting a nitrogenous
group in their biosyntheses which make two kinds of 5α-cevanine isosteroidal
alkaloids,  the  dihydrogen  of C- 13  and  C- 17  being  at  the  state  of
trans-configuration (e. g. verticine, verticinone) and at the state of cis-
configuration (e.g. delavine, chuanbeinone and songbeinine). Meanwhile, this
paper reports the existence and content of some 5α-cevanine isosteroidal alkaloids
in main Chinese fritillarias.  This result reveals that there may be a relationship
between the formation of characteristic constituents on one hand and other
morphological characters and distribution of the plants concerned on the other,
which encourages further investigation.

Key words: Liliaceae, Fritillaria L., Characteristic constituents, 5α-cevanine isosteroidal alkaloids