Welcome to Journal of University of Chinese Academy of Sciences,Today is

Analysis on the Relationship Between the Configuration and Optical Activity of Tartaric Acid and Glyceraldehyde

  • YIN YuYing ,
  • LIU ChunYun
Expand
  • Beijing Institute of Petrochemical Technology, Beijing 102600, China

Received date: 2003-01-20

  Revised date: 2003-06-30

  Online published: 2004-05-10

Abstract

On the basis of the helix theory proposed by the authors,the relationship between sructure and rotatory direction is analyzed for the tartaric acid and glyceraldehyde.The results show that there is a close correlation between structure and optical activity in both compounds even if they can form many hydrogen bonds.

Cite this article

YIN YuYing , LIU ChunYun . Analysis on the Relationship Between the Configuration and Optical Activity of Tartaric Acid and Glyceraldehyde[J]. Journal of University of Chinese Academy of Sciences, 2004 , 21(3) : 352 -357 . DOI: 10.7523/j.issn.2095-6134.2004.3.011

References

[1] 邢其毅, 徐瑞秋, 周政.基础有机化学.北京:高等教育出版社, 1980.298

[2] Potapov V M.Stereochemistry.Moscow:MIR Publishers, 1979.62-64

[3] Streitwieser Jr A, Heatacoc C H.Introduction to Organic Chemistry.2nd ed.New York:Macmillam Publishing Co, 1976.110

[4] Morrison R T, Boyd G N.Organic Chemistry.Allyn and Bacon,3rd ed.1973.Chapter 4

[5] Kagan H B.Stereochemistry.Vol.2.Stuttgart:Georg Thieme Publishers, 1977.43

[6] 高振衡.物理有机化学(上).北京:人民教育出版社, 1982.41-42

[7] 尹玉英, 刘春蕴.有机化合物分子旋光性的螺旋理论.北京:化工出版社, 2000

[8] Peerdeman A F, Van Bommel A J, Bijvoet J M.Pric.Acad.Sci.Amst., 1951, B54:16

[9] Brewster J H.Helix models of optical activity.In:topics stereochemistry.Vol.2.New York:John Wiley &Sons, 1967.1-72

[10] Hargeaves M K, Richardson P J.J.Chem.Soc., 1957, 2260

[11] Eliel E L,Wilen S H, Mander L N.Stereochemistry of organic compounds.New York:John Wiley &Sons,1974.1074

Outlines

/