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Crystal structure and dielectric properties of functional electronic ceramic CaSrTiMnO6

  • YAN Meng ,
  • TAN Yan-Qing ,
  • XIAO Xiao-Ling ,
  • HU Zhong-Bo ,
  • WU Mei-Mei ,
  • CHEN Dong-Feng
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  • 1. Graduate University, Chinese Academy of Sciences, Beijing 100049, China;
    2. China Institute of Atomic Energy, Beijing 102413, China

Received date: 2012-04-17

  Revised date: 2012-05-09

  Online published: 2012-05-09

Abstract

CaSrTiMnO6(CSTM) dielectric ceramic was synthesized by the solid-state reaction method. Rietveld refinement results indicate that the ceramic has orthorhombic structure with space group pnma. Only one dielectric relaxation was found in CSTM ceramic, and it can be well explained by the mixed-valent structure (Mn3+/Mn4+) and normalized bond length theory. Within a temperature range from 333 K to 453 K, the value of dielectric constant was nearly stabilized at 4 000 in low frequencies, which suggests its wide potential application in the field of high-temperature and low-frequency dielectric devices.

Cite this article

YAN Meng , TAN Yan-Qing , XIAO Xiao-Ling , HU Zhong-Bo , WU Mei-Mei , CHEN Dong-Feng . Crystal structure and dielectric properties of functional electronic ceramic CaSrTiMnO6[J]. Journal of University of Chinese Academy of Sciences, 2013 , 30(3) : 322 -328 . DOI: 10.7523/j.issn.1002-1175.2013.03.007

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