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Design and Synthesis of Nitrogen, Sulfur-Functional Group Based Ligands and the Structure of Related Coordination Supramolecular Complexes
Received date: 2002-11-21
Online published: 2003-01-18
Supported by
supported by NNSFC(29825103) and Chinese Academy of Sciences(KZCX2-H3)
We have explored several ways to design and prepare nitrogen-, sulfur-functional-groups based on ligands and the structure of related coordinationsupramolecular complexeswith one-dimensional (1D) chains, two-dimensional (2D) and three-dimensional (3D) net-works having organic molecular components and/or metal-metal interactions by using transi-tion metal ions and organic ligands. Summarizes their syntheses, structures and properties,including conductivity and magnetic properties. The following aspects are discussed: (1) a se-ries of metal supramolecular complexes; (2) design and synthesis of the ligands based on nitro-gen-sulfur- and carboxylate-fuctional groups and the structures of related complexes; and (3)studies of series of copper cyanide complexes.
Key words： supramolecular complex; self-assembly; design and synthesis
Zhao Yingjun , Cao Rong , Hong Maochun . Design and Synthesis of Nitrogen, Sulfur-Functional Group Based Ligands and the Structure of Related Coordination Supramolecular Complexes[J]. Journal of University of Chinese Academy of Sciences, 2003 , 20(1) : 112 -116 . DOI: 10.7523/j.issn.2095-6134.2003.1.018
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