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2025 , Vol. 42 >Issue 4: 450 - 459

DOI: https://doi.org/10.7523/j.ucas.2023.085

Research Articles

Adsorption of diclofenac sodium from wastewater by MIL-53(Fe) composite materials

  • CAI Yanrong ,
  • LI Xueyan ,
  • JIANG Weili ,
  • WANG Qiong ,
  • CHANG Chun
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  • 1. College of Chemistry and Materials Engineering, Bohai University, Jinzhou 121013, Liaoning, China;
    2. College of Environmental and Chemical Engineering, Dalian University, Dalian 116622, Liaoning, China

Received date: 2023-06-20

  Revised date: 2023-10-30

  Online published: 2023-12-12

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Abstract

Fe-MOF materials MIL-53 (Fe) and MIL-53 (Fe)-10FA were prepared by solvothermal method, and their adsorption properties for diclofenac sodium (DCF) in aqueous solution were investigated. The adsorption behavior of the two MOF materials to DCF follows the pseudo-second-order kinetic model, and the adsorption process belongs to chemical adsorption. The adsorption equilibrium isotherm conforms to the Langmuir adsorption isotherm model and is monolayer adsorption. The surface morphology of MIL-53 (Fe)-10FA modified by formic acid was different from that of MIL-53 (Fe). The crystal size was larger than that of MIL-53(Fe). The pore size, specific surface area and total pore volume increased after modified. The content of oxygen-containing functional groups also increased. The adsorption capacity of MIL-53 (Fe)-10FA for DCF was significant, and the maximum adsorption capacity of Langmuir isotherm fitting was 652.29 mg/g. The adsorption mechanism mainly includes hydrogen bonding and π-π stacking between benzene rings and benzene rings.

Key words： adsorption; MIL-53 (Fe); modification; diclofenac sodium

Cite this article

CAI Yanrong , LI Xueyan , JIANG Weili , WANG Qiong , CHANG Chun . Adsorption of diclofenac sodium from wastewater by MIL-53(Fe) composite materials[J]. Journal of University of Chinese Academy of Sciences, 2025 , 42(4) : 450 -459 . DOI: 10.7523/j.ucas.2023.085

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