Journal of University of Chinese Academy of Sciences >
Development strategies and emerging applications of thermoelectric polymer composites
Received date: 2025-01-25
Revised date: 2025-03-28
Online published: 2025-04-16
Devices made of thermoelectric materials can realize the interconversion between heat and electricity， which is based on the Seebeck effect and the Peltier effect respectively， without any moving elements. Different from conventional metallic and inorganic thermoelectric materials， thermoelectric polymer composites possess good flexibility， decent stretchability， and healing ability， thus arousing ever-increasing interests among researchers because they are abundant， inexpensive， light-weighted， low-toxic or non-toxic， and thermally less conductive. Generally， thermoelectric polymer composites comprise nanomaterials which are usually carbon nanotubes， graphene， metal organic frameworks， MXenes， black phosphorus， etc. and conductive polymers which are typically polythiophene and its derivatives， polyaniline， and polypyrrole. Apart from traditional use of generating electricity from heat for thermoelectric materials， polymer composites acting as an indispensable complement to inorganic thermoelectric materials have combined advantages of conductive polymers and nanomaterials and are finding new applications in various sensors although their performance in certain aspects remains below that of conventional metallic and inorganic thermoelectric materials. New toolkits like artificial intelligence and machine learning have been introduced as effective ways in facilitating efficient design， preparation， and performance enhancement of thermoelectric polymer composites. It is expected that thermoelectric polymer composites will make great progress and demonstrate many broader application scenarios.
Cunyue GUO , Peiyao LIU . Development strategies and emerging applications of thermoelectric polymer composites[J]. Journal of University of Chinese Academy of Sciences, 2026 , 43(2) : 155 -163 . DOI: 10.7523/j.ucas.2025.013
| [1] | Zhang Q， Sun Y M， Xu W， et al. Organic thermoelectric materials： emerging green energy materials converting heat to electricity directly and ef?ciently［J］. Adv Mater， 2014， 26： 6829-6851. DOI： 10.1002/adma.201305371 . |
| [2] | Hu Y J， Shi H， Song H J， et al. Effects of a proton scavenger on the thermoelectric performance of free-standing polythiophene and its derivative films［J］. Synth Met， 2013， 181： 23-26. DOI： 10.1016/j.synthmet.2013.08.006 . |
| [3] | Hao L P， Kang J Y， Shi J L， et al. Enhanced thermoelectric performance of poly（3-substituted thiophene）/single-walled carbon nanotube composites via polar side chain modification［J］. Compos Sci Technol， 2020， 199： 108359. DOI： 10.1016/j.compscitech.2020.108359 . |
| [4] | Lee Y H， Oh J W， Lee S-S， et al. Highly ordered nanoconfinement effect from evaporation-induced self-assembly of block copolymers on in situ polymerized PEDOT∶Tos［J］. ACS Macro Lett， 2017， 6（4）： 386-392. DOI： 10.1021/acsmacrolett.7b00137 . |
| [5] | Wu J S， Sun Y M， Xu W， et al. Investigating thermoelectric properties of doped polyaniline nanowires［J］. Synth Met， 2014， 189： 177-182. DOI： 10.1016/j.synthmet.2014.01.007 . |
| [6] | Liang L R， Chen G M， Guo C-Y. Polypyrrole nanostructures and their thermoelectric performance［J］. Mater Chem Front， 2017， 1（2）： 380-386. DOI： 10.1039/c6qm00061d . |
| [7] | Yao H Y， Fan Z， Cheng H L， et al. Recent development of thermoelectric polymers and composites［J］. Macromol Rapid Commun， 2018， 39： 1700727. DOI： 10.1002/marc.201700727 . |
| [8] | Park K T， Lee T M， Ko Y P， et al. High-performance thermoelectric fabric based on a stitched carbon nanotube fiber［J］. ACS Appl Mater Interfaces， 2021， 13（5）： 6257-6264. DOI： 10.1021/acsami.0c20252 . |
| [9] | Shalini V， Navaneethan M， Harish S， et al. Design and fabrication of PANI/GO nanocomposite for enhanced room-temperature thermoelectric application［J］. Appl Surf Sci， 2019， 493： 1350-1360. DOI： 10.1016/j.apsusc.2019.06.249 . |
| [10] | Rathi V， Singh K， Parmar K P S， et al. Boosting thermoelectric performance of PEDOT∶PSS/Bi2Te3 hybrid films via structural and interfacial engineering［J］. Org Electron， 2024， 133： 107103. DOI： 10.1016/j.orgel.2024.107103 . |
| [11] | Ju H， Park D B， Kim J H. Thermoelectric enhancement in multilayer thin-films of tin chalcogenide nanosheets/conductive polymers［J］. Nanoscale， 2019， 11（34）： 16114-16121. DOI： 10.1039/c9nr04712c . |
| [12] | Xu W J， Zhao Y J， Wang H R， et al. Postsynthetic-modified PANI/MOF composites with tunable thermoelectric and photoelectric properties［J］. Chem Eur J， 2021， 27（15）： 5011-5018. DOI： 10.1002/chem.202005474 . |
| [13] | Guan X， Feng W， Wang X Z， et al. Significant enhancement in the Seebeck coe?cient and power factor of p?type poly（3，4-ethylenedioxythiophene）∶poly（styrenesulfonate） through the incorporation of n?type MXene［J］. ACS Appl Mater Interfaces， 2020， 12（11）： 13013-13020. DOI： 10.1021/acsami.9b21185 . |
| [14] | Novak T G， Shin H S， Kim J M， et al. Low-cost black phosphorus nano fillers for improved thermoelectric performance in PEDOT∶PSS composite films［J］. ACS Appl Mater Interfaces， 2018， 10（21）： 17957-17962. DOI： 10.1021/acsami.8b03982 . |
| [15] | He J， Tritt T M. Advances in thermoelectric materials research： looking back and moving forward［J］. Science， 2017， 357： eaak9997. DOI： 10.1126/science.aak9997 . |
| [16] | Russ B， Glaudell A， Urban J J， et al. Organic thermoelectric materials for energy harvesting and temperature control［J］. Nat Rev Mater， 2016， 1： 16050. DOI： 10.1038/natrevmats.2016.50 . |
| [17] | Fan Z， Du D H， Guan X， et al. Polymer films with ultrahigh thermoelectric properties arising from significant seebeck coefficient enhancement by ion accumulation on surface［J］. Nano Energy， 2018， 51： 481-488. DOI： 10.1016/j.nanoen.2018.07.002 . |
| [18] | Liang L R， Gao C Y， Chen G M， et al. Large-area， stretchable， super flexible and mechanically-stable thermoelectric films of polymer/carbon nanotube composites［J］. J Mater Chem C， 2016， 4（3）： 526-532. DOI： 10.1039/c5tc03768a . |
| [19] | Wang L M， Yao Q， Xiao J X， et al. Engineered molecular chain ordering in single-walled carbon nanotubes/polyaniline composite films for high-performance organic thermoelectric materials［J］. Chem-Asian J， 2016， 11（12）： 1804-1810. DOI： 10.1002/asia.201600212 . |
| [20] | Wu X， Luo Q Y， Yin S X， et al. Organic/inorganic thermoelectric composites electrochemical synthesis， properties， and applications［J］. J Mater Sci， 2021， 56（35）： 19311-19328. DOI： 10.1007/s10853-021-06512-x . |
| [21] | Ibrahim N I， Wasfi A S. A comparative study of polyaniline/MWCNT with polyaniline/SWCNT nanocomposite films synthesized by microwave plasma polymerization［J］. Synth Met， 2019， 250： 49-54. DOI： 10.1016/j.synthmet.2019.02.007 . |
| [22] | Culebras M， Cho C Y， Krecker M， et al. High thermoelectric power factor organic thin films through combination of nanotube multilayer assembly and electrochemical polymerization［J］. ACS Appl Mater Interfaces， 2017， 9（7）： 6306-6313. DOI： 10.1021/acsami.6b15327 . |
| [23] | Nandihalli N， Liu C-J， Mori T. Polymer based thermoelectric nanocomposite materials and devices： fabrication and characteristics［J］. Nano Energy， 2020， 78： 105186. DOI： 10.1016/j.nanoen.2020.105186 . |
| [24] | Huo B C， Guo C-Y. Advances in thermoelectric composites consisting of conductive polymers and fillers with different architectures［J］. Molecules， 2022， 27： 6932. DOI： 10.3390/molecules27206932 . |
| [25] | Song E W， Liu P Y， Lv Y F， et al. Conductive polymer-based thermoelectric composites： preparation， properties， and applications［J］. J Compos Sci， 2024， 8（8）： 308. DOI： 10.3390/jcs8080308 . |
| [26] | Zhu M Y， He B Q， Zhang K， et al. Recent progress of poly（3-hexylthiophene）-based materials for thermoelectric applications［J］. Mater Chem Front， 2024， 8（13）： 2454-2492. DOI： 10.1039/d4qm00213j . |
| [27] | Fan W S， Guo C Y， Chen G M. Flexible films of poly（3，4-ethylenedioxythiophene）/carbon nanotube thermoelectric composites prepared by dynamic 3-phase interfacial electropolymerization and subsequent physical mixing［J］. J Mater Chem A， 2018， 6（26）： 12275-12280. DOI： 10.1039/c8ta04838j . |
| [28] | Fan W S， Liang L R， Zhang B B， et al. PEDOT thermoelectric composites with excellent power factors prepared by 3-phase interfacial electropolymerization and carbon nanotube chemical doping［J］. J Mater Chem A， 2019， 7（22）： 13687-13694. DOI： 10.1039/c9ta03153g . |
| [29] | Yin S X， Wu X， Wang R Y， et al. Composite aerogel of electropolymerized polyaniline and SWCNTs with high thermoelectric performance［J］. Macromol Mater Eng， 2022， 307（8）： 2200094. DOI： 10.1002/mame.202200094 . |
| [30] | Xiong J H， Jiang F X， Shi H， et al. Liquid exfoliated graphene as dopant for improving the thermoelectric power factor of conductive PEDOT∶PSS nanofilm with hydrazine treatment［J］. ACS Appl Mater Interfaces， 2015， 7（27）： 14917-14925. DOI： 10.1021/acsami.5b03692 . |
| [31] | Bae E J， Kang Y H， Jang K S， et al. Enhancement of thermoelectric properties of PEDOT∶PSS and tellurium-PEDOT∶PSS hybrid composites by simple chemical treatment［J］. Sci Rep， 2016， 6： 18805. DOI： 10.1038/srep18805 . |
| [32] | Gonzalez-Juarez M， Isaacs M A， Bradshaw D， et al. Enhanced thermoelectric properties of a semiconducting two dimensional metal-organic framework via iodine loading［J］. ACS Appl Mater Interfaces， 2023， 15（4）： 5478-5486. DOI： 10.1021/acsami.2c20770 . |
| [33] | Li K C， Wang J， Wang H. Recent advances of 2D conductive metal-organic frameworks in thermoelectrics［J］. J Mater Chem A， 2024， 12（24）： 14245-14267. DOI： 10.1039/d4ta01820f . |
| [34] | 江润璐， 吴鑫， 郭昊骋， 等. UiO-67基导电复合材料的制备及其热电性能研究［J］. 无机材料学报， 2023， 38（11）： 1338-1344. DOI： 10.15541/jim20230197 . |
| [35] | Ebrahim A， Ghali M， El-Moneim A A. Microporous Zr?metal?organic frameworks based?nanocomposites for thermoelectric applications［J］. Sci Rep， 2024， 14： 13067. DOI： 10.1038/s41598-024-62317-3 . |
| [36] | Wang G R， Mei Z Y， Li Y， et al. Flame-retardant thermoelectric responsive coating based on poly（3，4-ethylenedioxythiphene） modified metal-organic frameworks［J］. e-Polymers， 2024， 24（1）： 20230138. DOI： 10.1515/epoly-2023-0138 . |
| [37] | Luo Q Y， Wu X， Wang E Q， et al. Compositing nanostructured polyaniline with single-walled carbon nanotubes for high thermoelectric performance［J］. Int J Energy Res， 2023， 2023： 6989497. DOI： 10.1155/2023/6989497 . |
| [38] | Yin S X， Lu W T， Wu X， et al. Enhancing thermoelectric performance of polyaniline/single-walled carbon nanotubes composites via dimethyl sulfoxide-mediated electropolymerization［J］. ACS Appl Mater Interfaces， 2021， 13（3）： 3930-3936. DOI： 10.1021/acsami.0c19100 . |
| [39] | Li Y Y， Ai L K， Luo Q Y， et al. Compositing benzothieno［3，2-b］benzofuran derivatives with single-walled carbon nanotubes for enhanced thermoelectric performance［J］. Molecules， 2023， 28（18）： 6519. DOI： 10.3390/molecules28186519 . |
| [40] | Li Y Y， Dong J X， Wu X， et al. Elevating thermoelectric performance by compositing dibromo-substituted thienoacene with SWCNTs［J］. ACS Appl Mater Interfaces， 2024， 16（27）： 35190-35199. DOI： 10.1021/acsami.4c07042 . |
| [41] | Qu D W， Huang X， Li X， et al. Annular ?exible thermoelectric devices with integrated-module architecture［J］. npj Flexible Electron， 2020， 4（1）： 1. DOI： 10.1038/s41528-020-0064-2 . |
| [42] | Liang L R， Wang M M， Wang X D， et al. Initiating a stretchable， compressible， and wearable thermoelectric generator by a spiral architecture with ternary nanocomposites for efficient heat harvesting［J］. Adv Funct Mater， 2022， 32（15）： 2111435. DOI： 10.1002/adfm.202111435 . |
| [43] | Li H X， Ding Z F， Zhou Q， et al. Harness high?temperature thermal energy via elastic thermoelectric aerogels［J］. Nano-Micro Lett， 2024， 16（1）： 151. DOI： 10.1007/s40820-024-01370-z . |
| [44] | Li G， Chen C Z， Liu Z J， et al. Distinguishing thermoelectric and photoelectric modes enables intelligent real-time detection of indoor electrical safety hazards［J］. Mater Horiz， 2024， 11（7）： 1679. DOI： 10.1039/d3mh02187d . |
| [45] | Sun Q， Du C Y， Chen G M. Thermoelectric materials and applications in buildings［J］. Prog Mater Sci， 2025， 149： 101402. DOI： 10.1016/j.pmatsci.2024.101402 . |
| [46] | Liao Z X， Zhou X Y， Wei G Y， et al. Intrinsically self-healable and wearable all-organic thermoelectric composite with high electrical conductivity for heat harvesting［J］. ACS Appl Mater Interfaces， 2022， 14（38）： 43421-43430. DOI： 10.1021/acsami.2c13593 . |
| [47] | Wu X， Yin S X， Guo C Y. Self-healable and robust PE/PEDOT/SWCNT thermoelectric composites［J］. ACS Appl Mater Interfaces， 2022， 14（28）： 32056-32065. DOI： 10.1021/acsami.2c07490 . |
| [48] | Malik Y T， Akbar Z A， Seo J Y， et al. Self-healable organic-inorganic hybrid thermoelectric materials with excellent ionic thermoelectric properties［J］. Adv Energy Mater， 2022， 12（6）： 2103070. DOI： 10.1002/aenm.202103070 . |
| [49] | Hao Y Z， Zuo Y T， Zheng J Z， et al. Machine learning for predicting ultralow thermal conductivity and high ZT in complex thermoelectric materials［J］. ACS Appl Mater Interfaces， 2024， 16（36）： 47866-47878. DOI： 10.1021/acsami.4c09043 . |
| [50] | Ebrahimibagha D， Armida S A， Datta S， et al. Machine learning based models to investigate the thermoelectric performance of carbon nanotube-polyaniline nanocomposites［J］. Comput Mater Sci， 2024， 232： 112601. DOI： 10.1016/j.commatsci.2023.112601 . |
| [51] | Yang Y， Zhao G J， Cheng X， et al. Stretchable and healable conductive elastomer based on PEDOT∶PSS/natural rubber for self-powered temperature and strain sensing［J］. ACS Appl Mater Interfaces， 2021， 13（12）： 14599-14611. DOI： 10.1021/acsami.1c00879 . |
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