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中国科学院大学学报 ›› 2014, Vol. 31 ›› Issue (3): 329-336.DOI: 10.7523/j.issn.2095-6134.2014.03.006

• 大气颗粒物与空气污染专刊 • 上一篇    下一篇

北京秋季大气挥发性有机物及相关污染物特征分析

罗达通, 高健, 王淑兰, 张岳翀, 张萌, 柴发合   

  1. 中国环境科学研究院, 北京 100012
  • 收稿日期:2013-08-22 修回日期:2013-11-02 发布日期:2014-05-15
  • 通讯作者: 高健,E-mail:gaojian@craes.org.cn
  • 基金资助:

    国家自然科学基金(41005065、41375132)和国家环境保护公益性科研专项(201009001、201309011、201409003)资助

Characteristics of volatile organic compounds and relative pollutants observed in autumn in Beijing

LUO Datong, GAO Jian, WANG Shulan, ZHANG Yuechong, ZHANG Meng, CHAI Fahe   

  1. Chinese Research Academy of Environmental Sciences, Beijing 100012, China
  • Received:2013-08-22 Revised:2013-11-02 Published:2014-05-15

摘要:

综合分析北京地区典型秋季挥发性有机物(VOCs)及各相关污染物的污染水平以及日夜变化趋势,说明VOCs的组成和浓度特征.VOCs平均小时浓度为54.6ppb,其中,非甲烷碳氢化合物(NMHCs)为38.0ppb;含氧挥发性有机物(OVOCs)为10.4ppb.通过对VOCs特征组分的日夜变化和特征比值(E/E和B/T)的分析,发现研究区域大气老化现象明显,且受机动车尾气影响显著.结合后向气流轨迹分析和对采样期间正午时段的B/T值特征的解释,印证了以上结论.

关键词: 北京, 秋季, 挥发性有机物, 污染特征, 来源

Abstract:

Ninety-nine volatile organic compounds (VOCs) species were measured in autumn in Beijing. The average concentration of VOCs was 54.6 ppb. The average concentiations of NMHCs and oxygenated VOCs were 38.0 ppb and 10.04 ppb, respectively. The pollution status of VOCs was evaluated based on the diurnal variation and ratio between typical VOCs species(E/E and B/T). The air masses observed were characterized to photochemical-aged and supposed to be affected mainly by traffic emission sources. The same conclusion was reached by the co-analysis of air mass backward trajectory and B/T value at noon.

Key words: Beijing, autumn, VOCs, pollution level, source characteristics

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