环戊基甲基酮连氮的合成及表征

doi:10.7523/j.issn.2095-6134.2021.05.002

中国科学院大学学报 ›› 2021, Vol. 38 ›› Issue (5): 583-589.DOI: 10.7523/j.issn.2095-6134.2021.05.002

环戊基甲基酮连氮的合成及表征

赵鹏^1,2, 赵文昭^2,3, 夏洋峰^2,3, 刘龙², 张延强^2,4

1. 中国石油大学(北京)化学工程与环境学院, 北京 102249;
2. 中国科学院过程工程研究所中国科学院粉体材料技术重点实验室, 北京 100190;
3. 中国科学院大学化学工程学院, 北京 100049;
4. 郑州中科新兴产业技术研究院, 郑州 450000

收稿日期:2020-01-13 修回日期:2020-03-18 发布日期:2021-09-13
通讯作者: 张延强
基金资助:
国家自然科学基金（21676281，21878278）和北京市自然科学基金（2192054）资助

Synthesis and characterization of cyclopentyl methyl ketazine

ZHAO Peng^1,2, ZHAO Wenzhao^2,3, XIA Yangfeng^2,3, LIU Long², ZHANG Yanqiang^2,4

1. College of Chemical Engineering and Environment, China University of Petroleum, Beijing 102249, China;
2. Key Laboratory of Science and Technology on Particle Materials of CAS, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
3. School of Chemical Engineering, University of Chinese Academy of Sciences, Beijing 100049, China;
4. Zhengzhou Institute of Emerging Industrial Technology, Zhengzhou 450000, China

Received:2020-01-13 Revised:2020-03-18 Published:2021-09-13

摘要/Abstract

摘要： 以环戊基甲基酮和水合肼为原料，合成一种新的酮连氮化合物（环戊基甲基酮连氮，C₁₄N₂H₂₄），采用¹H NMR、¹³C NMR和IR表征确认产物的结构，并通过Gaussian 09计算对产物分子构型进行解析，表明（1E，2E）为最稳定构型；同时测定环戊基甲基酮连氮在常压下的基本物理化学性质，包括沸点（T_b，238.4℃）、熔点（T_m，-38.2℃）、密度（ρ，0.910~0.969 g·cm^-3）、动态黏度（η，2.35~13.17 mPa·s）和比热容（C_p，2.97~3.63 J·g^-1·℃^-1），并根据密度计算其等压热膨胀系数（α，8.26×10^-4~8.75×10^-4℃^-1）。结果显示ρ、η与温度呈负相关，C_p、α与温度呈正相关。

关键词: 环戊基甲基酮, 环戊基甲基酮连氮, 红外, 密度, 比热容

Abstract: In this paper, a new ketazine compound (C₁₄N₂H₂₄) was synthesized from cyclopentyl methyl ketone and hydrazine hydrate. After the separation and purification of the product, the structure of cyclopentyl methyl ketazinewas determined by ¹H NMR,¹³C NMR, and IR spectra. With Gaussian 09 computation, the structure (1E, 2E) of the product was proved to be the most stable molecular configuration. Furthermore, the basic physical and chemical properties of cyclopentyl methyl ketazine under atmospheric pressure were measured, including boiling point (T_b, 238.4℃), melting point (T_m, -38.2℃), density (ρ, 0.910-0.969 g·cm^-3), dynamic viscosity (η,2.35-13.17 mPa·s), and specific heat capacity (C_p, 2.97-3.63 J·g^-1·℃^-1). The thermal expansion coefficient (α, 8.26×10^-4-8.75×10^-4℃^-1) was calculated according to its density.The results show that ρ and η have a positive correlation with temperature while C_p and α have a negative correlation with temperature. The obtained data and correlation formula are very valuable for the industrial application of cyclopentyl methyl ketazine.

Key words: cyclopentyl methyl ketone, cyclopentyl methyl ketazine, infrared, density, specific heat capacity

中图分类号:

赵鹏, 赵文昭, 夏洋峰, 刘龙, 张延强. 环戊基甲基酮连氮的合成及表征[J]. 中国科学院大学学报, 2021, 38(5): 583-589.

ZHAO Peng, ZHAO Wenzhao, XIA Yangfeng, LIU Long, ZHANG Yanqiang. Synthesis and characterization of cyclopentyl methyl ketazine[J]. Journal of University of Chinese Academy of Sciences, 2021, 38(5): 583-589.

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环戊基甲基酮连氮的合成及表征

Synthesis and characterization of cyclopentyl methyl ketazine

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