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›› 2015, Vol. 32 ›› Issue (1): 46-50.DOI: 10.7523/j.issn.2095-6134.2015.01.008

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Structure and magnetic and electronic properties of CoFe1.9Nb0.1O4

YU Yuan, HAO Yongmei   

  1. College of Chemistry and Chemical Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
  • Received:2014-03-17 Revised:2014-04-29 Online:2015-01-15

Abstract:

CoFe1.9Nb0.1O4 phase was synthesized through solid-state reaction. Rietveld refinement shows that it has cubic spinel structure in the Fd-3m space group. Nb replaces Fe mainly in B site, leading to significant effects on the magnetic and electronic properties. The substitution weakens the ferromagnetic property of CoFe2O4, but improves its dielectric characteristics. An obvious dielectric relaxor behavior is observed in CoFe1.9Nb0.1O4, which is mainly attributed to the mixed-valence of Fe induced by the Nb-doping. Because of high-leakage current of CoFe1.9Nb0.1O4, only a P-E loop of low-quality is recorded.

Key words: ferrite, multiferroic, dielectric, magnetic property, Nb-doping

CLC Number: