Syntheses of 1, 3-bis (aryl butadienyl ketone) propane derivatives and their visible light photocatalytic[4+4]and[2+2]cycloadditions

doi:10.7523/j.issn.2095-6134.2012.2.006

Abstract

Abstract:

New bisconjugated compounds, 1, 3-bis (aryl butadienyl ketone) propane derivatives with F, Cl, Br, and 2-naphthyl substituents, were synthesized via double Wittig reactions. Their visible light irradiated photocatalytic intramolecular[4+4]and[2+2]cycloadditions were realized in the presence of Ru(bipy)₃Cl₂ as catalyst.

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Key words: aryl butadienyl ketone, visible light photocatalytic, cycloaddition, ion radical, cyclooctane

CLC Number:

O625.42

LIU Li-Qiang, YANG Jing-Kui. Syntheses of 1, 3-bis (aryl butadienyl ketone) propane derivatives and their visible light photocatalytic[4+4]and[2+2]cycloadditions[J]. , 2012, (2): 180-191.

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