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中国科学院大学学报 ›› 2006, Vol. 23 ›› Issue (4): 433-441.DOI: 10.7523/j.issn.2095-6134.2006.4.001

• 综述 •    下一篇

有机硅-丙烯酸树脂共聚方法述评

曹顺生; 刘白玲; 邓小波; 罗 荣; 陈华林   

  1. 中国科学院成都有机化学研究所,成都 610041
  • 收稿日期:1900-01-01 修回日期:1900-01-01 发布日期:2006-07-15

A Review on Methods of Organic Silicone-Acrylate Copolymerisation

CAO Shun-Sheng, LIU Bai-Ling, DENG Xiao-Bo, LUO Rong, CHEN Hua-Lin   

  1. Chengdu Institute of Organic Chemistry, the Graduate School of CAS, Chinese Academy of Sciences, Chengdu 610041, P. R. China
  • Received:1900-01-01 Revised:1900-01-01 Published:2006-07-15

摘要: 有机硅具有低表面张力,低玻璃化温度、良好的耐水、耐温、耐候等性能,这些优越性能为有机硅在高分子材料科学中的应用起着极为重要的作用。然而,由于有机硅的成本高、附着力及成膜性能较差,使它的进一步应用受到限制。鉴于此,许多有机硅工作者利用丙烯酸类物质对有机硅进行改性,不仅可以改善有机硅的缺点,而且还可以赋予这种复合材料许多新的性能。近年来,随着有机硅-丙烯酸树脂共聚物研究的不断深入,各种聚合方法也不断涌现。本文将以有机硅-丙烯酸树脂复合材料的类型为基础,对其中一些主要聚合方法的原理、优、缺点以及应用进行了比较详细的述评。

关键词: 有机硅, 丙烯酸酯, 共聚方法, 综述

Abstract: Organic siloxane and its polymer, due to the obvious advantages on the water repellency, weather resistance, low glass transition temperature and low surface energy etc, have a diversity of applications in polymer materials field. Its application, however, is subject to some limit due to high-cost, poor cohesiveness and poor film-forming property. Many efforts have been made to resolve these problems; presently polyacrylate is used to copolymerization. This copolymer not only overcomes such flaws, but also creates many new properties of the composite materials. In recent years, many methods have been reporting in literature with the study of copolymer. As a result, the purpose of this paper is to review with some details the primary methods.

Key words: organic silicone, acrylate, copolymerization

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