Design and Synthesis of Nitrogen, Sulfur-Functional Group Based Ligands and the Structure of Related Coordination Supramolecular Complexes

doi:10.7523/j.issn.2095-6134.2003.1.018

›› 2003, Vol. 20 ›› Issue (1): 112-116.DOI: 10.7523/j.issn.2095-6134.2003.1.018

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Design and Synthesis of Nitrogen, Sulfur-Functional Group Based Ligands and the Structure of Related Coordination Supramolecular Complexes

Zhao Yingjun, Cao Rong, Hong Maochun

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Received:2002-11-21 Online:2003-01-18
Supported by:
supported by NNSFC(29825103) and Chinese Academy of Sciences(KZCX2-H3)

Abstract

Abstract:

We have explored several ways to design and prepare nitrogen-, sulfur-functional-groups based on ligands and the structure of related coordinationsupramolecular complexeswith one-dimensional (1D) chains, two-dimensional (2D) and three-dimensional (3D) net-works having organic molecular components and/or metal-metal interactions by using transi-tion metal ions and organic ligands. Summarizes their syntheses, structures and properties,including conductivity and magnetic properties. The following aspects are discussed: (1) a se-ries of metal supramolecular complexes; (2) design and synthesis of the ligands based on nitro-gen-sulfur- and carboxylate-fuctional groups and the structures of related complexes; and (3)studies of series of copper cyanide complexes.

Key words: supramolecular complex, self-assembly, design and synthesis

CLC Number:

O641.4

Zhao Yingjun, Cao Rong, Hong Maochun. Design and Synthesis of Nitrogen, Sulfur-Functional Group Based Ligands and the Structure of Related Coordination Supramolecular Complexes[J]. , 2003, 20(1): 112-116.

References

[1] Yaghi O M Li H, Davis C, Richardson D, Groy T L. Synthetic Strategies, Structure Patterns, and Emerging Properties in the Chemistry of Modular Porous Solids. Acc Chem Res, 1998, 31:474~484

[2] Li H, Eddaoudi M, O' Keeffe M, Yaghi O M. Design and synthesis of an exceptionally stable and highly porous metal-organic framework. Nature, 2000, 402:276~279

[3] Mitzi D B. Synthesis, Structure, and Properties of Organic-Inorganic Perovskites and Related Materials. Prog Inorg Chem, 1999,48: 1~121

[4] Stupp S I, Braun P V. Molecular Manipulation of Microstructures: Biomaterials Ceranics and Semiconductors. Science, 1997, 277:1242~1248

[5] Mitzi D B, Wang S, Field C A, Chess C A, Guloy A M. Conducting Layered Organic-InorganicNalides containing <110>-Oriented Pervoskite Sheets. Science, 1995,267: 1473~ 1476

[6] Matsumoto N, Sunatsuki Y, Miyasaka H, Hashimoto Y, Luneau D, Tuchagues J P. [{Mn(salen)CN}] n: The First One-Dimensional Chain with Alternating High-Spin and Low-Spin MnⅢCenters Exhibits Metamagnetism. Angew Chem Int Ed, 1999, 38:171~173

[7] Seo J S, Whang D, Lee H, Jun S I, Oh J, Jeon Y J, Kim K. A homochiral metal-organic porous material for enantioselective separation and catalys, Nature, 2000, 404:982~986

[8] Hong M C, ZhaoY J, Su W P, Cao R, Fujita M, Zhou Z Y, Chan A S C. A Nanometer-Sized Metallosupramolecular Cube with Oh Symmetry. J Am Chem Soc, 2000, 122:4819~4820

[9] Hong M C, Zhao Y J, Su W P, Cao R, Fujita M, Zhou Z Y, Chan A S C. A Silver(I) Coordination Polymer Chain Containing Nanosized Tubes with Anionic and Solvent Molecule Guests. Angew Chem Int Ed, 2000, 39:2468~2470

[10] Zhao Y J, Hong M C, Liang Y C, Cao R, Li W J, Weng J B, Lu S F. A Paramagnetic Lamellar Polymer with a high Semiconducty.Chem Commun, 2001, 1020~1021

[11] Zhao Ying-Jun, Hong Mao-Chun, Su Wei-Ping, Cao Rong. Syntheses and Characterizations of two Copper Cyanide Complexes with Hexagonal Cu6Units. J Chem Soc Dalton Trans, 2000, 1685~1686

Design and Synthesis of Nitrogen, Sulfur-Functional Group Based Ligands and the Structure of Related Coordination Supramolecular Complexes

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