Shape-dependent effects of nanoceria on the activity of Pd/CeO2 catalysts for CO oxidation

doi:10.7523/j.issn.2095-6134.2015.05.004

Abstract

Abstract:

The redox property of palladium nanoparticles (NPs) is pivotal to CeO₂ supported Pd catalysts in oxidation reactions and is closely related to the structure of Pd-CeO₂ interface. Herein, we report that low-temperature CO oxidation activity of Pd/CeO₂ highly depends on the shape and crystal plane of CeO₂ supports. Pd/CeO₂ catalysts with CeO₂ nanoocthedrons (NOCs) and nanocubes (NCs) as supports were prepared by colloidal-deposition method. Results show that Pd/CeO₂ NOCs with ceria {111} facets enclosed exhibited much higher catalytic activity than Pd/CeO₂NCs with ceria {100} facets exposed. DFT calculations revealed that the redox property of surface Pd species may play important roles in determining the reducibility and activity of catalysts. The PdO_x to Pd cycle is more facile on Pd₄@CeO₂(111) than on Pd₄@CeO₂(100), which is dictated by the Pd-ceria interaction in the end. Our results show that the redox property of surface Pd is pivotal to the reducibility and activity of Pd/ceria catalysts, which could be tuned by manipulation of the Pd-CeO₂ interaction via tuning the exposed facets of ceria support.

Key words: Pd/CeO₂ interface, shape-dependent, CO oxidation, nanocube, nanooctahedron

CLC Number:

WANG Lei, MAO Junyi, YUAN Qing, HUANG Tao. Shape-dependent effects of nanoceria on the activity of Pd/CeO₂ catalysts for CO oxidation[J]. , 2015, 32(5): 594-604.

References

[1] Luo M F, Hou Z Y, Yuan X X, et al. Characterization study of CeO₂supported pd catalyst for low-temperature carbon monoxide oxidation[J]. Catal Lett, 1998, 50(3/4):205-209.

[2] Zhu H Q, Qin Z F, Shan W J, et al. Low-temperature oxidation of co over Pd/CeO₂-TiO₂ catalysts with different pretreatments[J]. J Catal, 2005, 233(1):41-50.

[3] Glaspell G, Hassan H M A, Elzatahry A, et al. Nanocatalysis on supported oxides for co oxidation[J]. Top Catal, 2008, 47(1/2):22-31.

[4] Hegde M S, Madras G, Patil K C. Noble metal ionic catalysts[J]. Accounts Chem Res, 2009, 42(6):704-712.

[5] Wang B, Weng D A, Wu X D, et al. Modification of Pd-CeO₂ catalyst by different treatments:effect on the structure and co oxidation activity[J]. Appl Surf Sci, 2011, 257(9):3878-3883.

[6] Idriss H, Diagne C, Hindermann J P, et al. Reactions of acetaldehyde on ceria and ceria-supported catalysts[J]. J Catal, 1995, 155(2):219-237.

[7] Bunluesin T, Gorte R J,Graham G W. Studies of the water-gas-shift reaction on ceria-supported Pt, Pd, and Rh:implications for oxygen-storage properties[J]. Appl Catal B-Environ, 1998, 15(1/2):107-114.

[8] Craciun R, Daniell W,Knozinger H. The effect of CeO₂ structure on the activity of supported pd catalysts used for methane steam reforming[J]. Appl Catal A-Gen, 2002, 230(1/2):153-168.

[9] Boronin A I, Slavinskaya E M, Danilova I G, et al. Investigation of palladium interaction with cerium oxide and its state in catalysts for low-temperature co oxidation[J]. Catal Today, 2009, 144(3/4):201-211.

[10] Meng L, Jia A-P, Lu J Q, et al. Synergetic effects of pdo species on co oxidation over PdO-CeO₂ catalysts[J]. J Phys Chem C, 2011, 115(40):19789-19796.

[11] Hadi A,Yaacob, II. Synthesis of pdo/ceo₂ mixed oxides catalyst for automotive exhaust emissions control[J]. Catal Today, 2004, 96(3):165-170.

[12] Zhu H Q, Qin Z F, Shan W J, et al. Pd/CeO₂-TiO₂ catalyst for co oxidation at low temperature:A tpr study with H₂ and co as reducing agents[J]. J Catal, 2004, 225(2):267-277.

[13] Luo M F, Pu Z Y, He M, et al. Characterization of PdO/Ce_0.8Y_0.2O_1.9 catalysts for carbon monoxide and methane oxidation[J]. J Mol Catal A-Chem, 2006, 260(1/2):152-156.

[14] Oh S H, Hoflund G B. Chemical state study of palladium powder and ceria-supported palladium during low-temperature co oxidation[J]. J Phys Chem A, 2006, 110(24):7609-7613.

[15] Chiesa M, Giamello E, Di Valentin C, et al. Nature of the chemical bond between metal atoms and oxide surfaces:new evidences from spin density studies of k atoms on alkaline earth oxides[J]. J Am Chem Soc, 2005, 127(48):16935-16944.

[16] Lu J, Serna P, Aydin C, et al. Supported molecular iridium catalysts:resolving effects of metal nuclearity and supports as ligands[J]. J Am Chem Soc, 2011, 133(40):16186-16195.

[17] Si R, Flytzani-Stephanopoulos M. Shape and crystal-plane effects of nanoscale ceria on the activity of Au-CeO₂ catalysts for the water-gas shift reaction[J]. Angew Chem Int Edit, 2008, 47(15):2884-2887.

[18] Boucher M B, Goergen S, Yi N, et al. 'Shape effects' in metal oxide supported nanoscale gold catalysts[J]. Phys Chem Chem Phys, 2011, 13(7):2517-2527.

[19] Yi N, Si R, Saltsburg H, et al. Active gold species on cerium oxide nanoshapes for methanol steam reforming and the water gas shift reactions[J]. Energy Environ Sci, 2010, 3(6):831-837.

[20] Zhou K B, Li Y D. Catalysis based on nanocrystals with well-defined facets[J]. Angew Chem Int Edit 2012, 51(3):602-613.

[21] Nolan M, Parker S C, Watson G W. Reduction of NO₂ on ceria surfaces[J]. J Phys Chem B, 2006, 110(5):2256-2262.

[22] Shapovalov V, Metiu H. Catalysis by doped oxides:Co oxidation by Au_xCe_1-xO₂[J]. J Catal, 2007, 245(1):205-214.

[23] Yang Z, Zhansheng L A, Luo G, et al. Oxygen vacancy formation energy at the Pd/CeO₂(111) interface[J]. Phys Lett A, 2007, 369(1/2):132-139.

[24] Herman G S. Characterization of surface defects on epitaxial CeO₂(001) films[J]. Surf Sci, 1999, 437(1/2):207-214.

[25] Skorodumova N V, Baudin M, Hermansson K. Surface properties of CeO₂ from first principles[J]. Phys Rev B, 2004, 69(7):075401.

[26] Yao H C,Yao Y F Y Ceria n automotive exhaust catalysts. 1. Oxygen storage[J]. J Catal, 1984, 86(2):254-265.

[27] Sayle D C, Maicaneanu S A, Watson G W. Atomistic models for CeO₂(111), (110), and (100) nanoparticles, supported on yttrium-stabilized zirconia[J]. J Am Chem Soc, 2002, 124(38):11429-11439.

[28] Nolan M, Parker S C,Watson G W. The electronic structure of oxygen vacancy defects at the low index surfaces of ceria[J]. Surf Sci, 2005, 595(1-3):223-232.

[29] Baudin M, Wojcik M, Hermansson K. Dynamics, structure and energetics of the (111), (011) and (001) surfaces of ceria[J]. Surf Sci, 2000, 468(1-3):51-61.

[30] Herman G S. Surface structure determination of CeO₂(001) by angle-resolved mass spectroscopy of recoiled ions[J]. Phys Rev B, 1999, 59(23):14899-14902.

[31] Norenberg H, Harding J H. The surface structure of CeO₂(001) single crystals studied by elevated temperature stm[J]. Surf Sci, 2001, 477(1):17-24.

[32] Putta C B, Ghosh S. Palladium nanoparticles on amphiphilic carbon spheres:a green catalyst for suzuki-miyaura reaction[J]. Adv Synth Catal, 2011, 353(11/12):1889-1896.

[33] Priolkar K R, Bera P, Sarode P R, et al. Formation of Ce_1-xPd_xO_2-delta solid solution in combustion-synthesized Pd/CeO₂ catalyst:xrd, xps, and exafs investigation[J]. Chem Mat, 2002, 14(5):2120-2128.

[34] Meng L, Jia A P, Lu J Q, et al. Synergetic effects of PdO species on co oxidation over PdO-CeO₂ catalysts[J]. J Phys Chem C, 2011, 115(40):19789-19796.

[35] Fernandez-Garcia M, Martinez-Arias A, Salamanca L N, et al. Influence of ceria on pd activity for the CO+O₂ reaction[J]. J Catal, 1999, 187(2):474-485.

[36] Hinokuma S, Fujii H, Okamoto M, et al. Metallic pd nanoparticles formed by Pd-O-Ce interaction:a reason for sintering-induced activation for co oxidation[J]. Chem Mat, 2010, 22(22):6183-6190.

[37] Hirvi J T, Kinnunen T J J, Suvanto M, et al. CO oxidation on PdO surfaces[J]. J Chem Phys, 2010, 133(8):084706.

[38] Chen Y, Hu P, Lee M H, et al. Au on (111) and (110) surfaces of CeO₂:a density-functional theory study[J]. Surf Sci, 2008, 602(10):1736-1741.

[39] Zhang C J, Michaelides A, King D A, et al. Anchoring sites for initial au nucleation on CeO₂{111}:O vacancy versus Ce vacancy[J]. J Phys Chem C, 2009, 113(16):6411-6417.

Shape-dependent effects of nanoceria on the activity of Pd/CeO₂ catalysts for CO oxidation

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