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中国科学院大学学报 ›› 2008, Vol. 25 ›› Issue (1): 136-143.DOI: 10.7523/j.issn.2095-6134.2008.1.019

• 优秀博士论文 • 上一篇    

有机共轭体系的设计与组装

李勇军a,b, 李玉良a,*, 朱道本a,*   

  1. a.中国科学院化学研究所有机固体院重点实验室 北京 100080
    b.中国科学院研究生院 北京 100049
  • 收稿日期:1900-01-01 修回日期:1900-01-01 发布日期:2008-01-15

Synthesis and Self-assemble of Organic π-conjugated Systems

Yongjun Lia,b, Yuliang Lia,*, Daoben Zhua   

  1. a. Key Laboratory of Organic Solids, Center for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, P. R. China,
    b. Graduate School, Chinese Academy of Sciences, Beijing 100049, P. R. China
  • Received:1900-01-01 Revised:1900-01-01 Published:2008-01-15

摘要: 本论文围绕有机共扼大π体系这一主题,利用共价键、配位键及弱相互作用如氢键、π-π堆积、亲水-疏水作用设计了一系列自组装超分子结构,在具有光电转换性能的给受体系、配位聚合物、光驱动的分子机器、空心胶囊等几个方面开展了一系列研究工作。

Abstract: Organic π-conjugated systems such as porphyrin, perylene bisimide, pyrene, fullerene, ferrocene have been synthesized and their self-assemble based on specific molecular interaction have been studied. The self-assemble into more complicated systems such as molecular machine and light-to-current converter have also been studied.

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